Department of Physics, Michigan Technological University, Houghton, Michigan 49931, United States.
ACS Nano. 2010 Nov 23;4(11):6760-6. doi: 10.1021/nn100925g. Epub 2010 Oct 18.
We have created PMMA-CNT matrices by embedding opened-tip vertically aligned multiwalled carbon nanotubes (VA-MWCNTs) with poly(methyl methacrylate) (PMMA). These PMMA-CNT matrices are excellent electron field emitters with an emission threshold field of 1.675 V/μm, more than 2-fold lower that that of the as-grown sample. In addition, the emission site density from these matrices is high, merely filling up the entire sample surface. Emission stability test at ∼1.35 mA/cm(2) was performed continuously for 40 h with no significant degradation. On the basis of our theoretical simulation and hypothetical modeling, we attribute these performances to the reduced screening effect and fewer Joule heatings due to the shorter effective transport distance of the electrons in MWCNTs.
我们通过嵌入开口端垂直排列多壁碳纳米管(VA-MWCNTs)和聚甲基丙烯酸甲酯(PMMA)制备了 PMMA-CNT 矩阵。这些 PMMA-CNT 矩阵是出色的电子场发射器,其发射阈值场为 1.675 V/μm,比原始样品低 2 倍以上。此外,这些矩阵的发射位点密度很高,几乎覆盖整个样品表面。在约 1.35 mA/cm(2)的发射稳定性测试中,我们持续进行了 40 小时,没有明显的退化。基于我们的理论模拟和假设建模,我们将这些性能归因于电子在 MWCNTs 中的有效传输距离较短,导致屏蔽效应降低和焦耳加热减少。