手性磁金属有机框架的 Mn(II)与非手性四唑基配体的自发拆分。
Chiral magnetic metal-organic frameworks of Mn(II) with achiral tetrazolate-based ligands by spontaneous resolution.
机构信息
Department of Chemistry, and Tianjin Key Lab on Metal and Molecule-based Material Chemistry, Nankai University, Tianjin 300071, China.
出版信息
Chem Commun (Camb). 2010 Dec 7;46(45):8543-5. doi: 10.1039/c0cc03111a. Epub 2010 Oct 19.
PMID:20959904
Abstract
The enantiomers of complex 1 (1a and 1b) have been obtained by spontaneous resolution upon crystallization in the absence of a chiral source. The enantiomeric nature of 1a and 1b was confirmed by circular dichroism (CD) spectra and theoretical investigation.
摘要
手性复合物 1（1a 和 1b）通过无手性源的结晶自发拆分得到对映异构体。通过圆二色性（CD）光谱和理论研究证实了 1a 和 1b 的对映体性质。
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