氰桥异双核分子正方形中[Fe(II)LSCo(III)LS]2 ⇔ [Fe(III)LSCo(II)HS]2 的光致转换。
[Fe(II)LSCo(III)LS]2 ⇔ [Fe(III)LSCo(II)HS]2 photoinduced conversion in a cyanide-bridged heterobimetallic molecular square.
机构信息
Institut Parisien de Chimie Moléculaire, Université Pierre et Marie Curie-Paris 6, UMR 7201, F-75252 Paris, France.
出版信息
Chem Commun (Camb). 2010 Dec 21;46(47):8995-7. doi: 10.1039/c0cc02024a. Epub 2010 Oct 22.
PMID:20967367
Abstract
The self-assembly of Fe(III){B(pz)(4)}(CN)(3) and Co(II)(bik)(2)(S)(2) affords the diamagnetic cyanide-bridged Fe(II)(LS)Co(III)(LS) molecular square which is converted into the corresponding magnetic Fe(III)(LS)Co(II)(HS) species under light irradiation at relatively low temperatures.
摘要
[Fe(III){B(pz)(4)}(CN)(3)]-和[Co(II)(bik)(2)(S)(2)]2+的自组装提供了反磁性氰桥联[Fe(II)(LS)Co(III)(LS)]2 分子正方形，该分子正方形在相对较低的温度下通过光照射转化为相应的磁性[Fe(III)(LS)Co(II)(HS)]2 物种。
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