Department of Physics, University of Isfahan, Isfahan 81746, Iran.
J Chem Phys. 2010 Nov 7;133(17):174702. doi: 10.1063/1.3497039.
We investigate the effect of monopolar charge disorder on the classical fluctuation-induced interactions between randomly charged net-neutral dielectric slabs and discuss various generalizations of recent results [A. Naji et al., Phys. Rev. Lett. 104, 060601 (2010)] to highly inhomogeneous dielectric systems with and without statistical disorder correlations. We shall focus on the specific case of two generally dissimilar plane-parallel slabs, which interact across vacuum or an arbitrary intervening dielectric medium. Monopolar charge disorder is considered to be present on the bounding surfaces and/or in the bulk of the slabs, may be in general quenched or annealed and may possess a finite lateral correlation length reflecting possible "patchiness" of the random charge distribution. In the case of quenched disorder, the bulk disorder is shown to give rise to an additive long-range contribution to the total force, which decays as the inverse distance between the slabs and may be attractive or repulsive depending on the dielectric constants of the slabs. By contrast, the force induced by annealed disorder in general combines with the underlying van der Waals forces in a nonadditive fashion, and the net force decays as an inverse cube law at large separations. We show, however, that in the case of two dissimilar slabs, the net effect due to the interplay between the disorder-induced and the pure van der Waals interactions can lead to a variety of unusual nonmonotonic interaction profiles between the dielectric slabs. In particular, when the intervening medium has a larger dielectric constant than the two slabs, we find that the net interaction can become repulsive and exhibit a potential barrier, while the underlying van der Waals force is attractive. On the contrary, when the intervening medium has a dielectric constant between that of the two slabs, the net interaction can become attractive and exhibit a free energy minimum, while the pure van der Waals force is repulsive. Therefore, the charge disorder, if present, can drastically alter the effective interaction between net-neutral objects.
我们研究了单极电荷无序对随机带电电中性介电片之间经典涨落诱导相互作用的影响,并讨论了对具有和不具有统计无序相关性的高度非均匀介电系统的最近结果[A. Naji 等人,Phys. Rev. Lett. 104, 060601 (2010)]的各种推广。我们将重点关注两个通常不同的平面平行板的具体情况,它们通过真空或任意中间介电介质相互作用。单极电荷无序被认为存在于边界表面和/或板体内部,可以是淬火或退火的,并且可能具有有限的横向相关长度,反映出随机电荷分布的可能“斑块性”。在淬火无序的情况下,体无序会导致总力的附加长程贡献,该贡献随板之间的距离的倒数衰减,并且取决于板的介电常数,可以是吸引的或排斥的。相比之下,退火无序引起的力通常以非加和的方式与基础范德瓦尔斯力相结合,并且在大的分离时,净力按立方反比律衰减。然而,我们表明,在两个不同的板的情况下,由于无序诱导和纯范德瓦尔斯相互作用之间的相互作用,净效应可以导致介电板之间的各种异常非单调相互作用分布。特别是,当中间介质的介电常数大于两个板时,我们发现净相互作用可以变得排斥并表现出势垒,而基础范德瓦尔斯力是吸引的。相反,当中间介质的介电常数在两个板之间时,净相互作用可以变得吸引并表现出自由能最小,而纯范德瓦尔斯力是排斥的。因此,如果存在电荷无序,它可以极大地改变净中性物体之间的有效相互作用。