School of Mechanical and Aerospace Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore.
Anal Bioanal Chem. 2011 Jan;399(3):1233-43. doi: 10.1007/s00216-010-4385-1. Epub 2010 Nov 8.
A chemo-electro-mechanical model is presented in this paper for transient simulation of the characteristics of the kinetic ionic-strength-sensitive hydrogel. It is termed the multi-effect-coupling ionic-strength-stimulus (MECis) model and it couples the chemical and electrical as well as mechanical effects together to predict responsive characteristics of the smart hydrogel to the ionic-strength stimulus of an environmental solution based on the laws of conservation of mass and momentum. The kinetic deforming characteristics simulated by the MECis model are compared with the experiments and achieve a good agreement. Then, the influence of the initial fixed charge density, as a material property of the hydrogel, on the kinetics of the ionic-strength-sensitive hydrogel is transiently analyzed, providing a deep view of the kinetics performance of the smart hydrogel.
本文提出了一个用于瞬态模拟动力学离子强度敏感水凝胶特性的化学-电-机械模型。该模型被称为多效应耦合离子强度刺激(MECis)模型,它基于质量和动量守恒定律,将化学、电和机械效应耦合在一起,根据环境溶液的离子强度刺激来预测智能水凝胶的响应特性。通过 MECis 模型模拟的动力学变形特性与实验进行了比较,吻合较好。然后,瞬态分析了水凝胶的初始固定电荷密度(作为水凝胶的材料特性)对离子强度敏感水凝胶动力学的影响,深入了解了智能水凝胶的动力学性能。