Liu Chang-Geng, Zhang Pan-Yue, Zeng Guang-Ming, Liu Yong-Gang
College of Environmental Science and Engineering, Hunan University, Changsha 410082, China.
Huan Jing Ke Xue. 2010 Sep;31(9):2124-8.
Bioleaching-dual polyaluminum chloride (PAC) and polyacrylamide (PAM) addition was used to condition sewage sludge. The results showed that FeSO4 x 7H2O addition improved the bioleaching rate obviously with a fixed sulfur power dosage of 3 g x L(-1); when the FeSO4 x 7H2O dosage was 8 g x L(-1), the bioleaching lasted 1.5 d to decrease the sludge pH below 2. Bioleaching improved the sludge dewaterability significantly with a specific resistance to filtration (SRF) reduction of 77.52% from 6.45 x 10(10)s2 x g(-10 to 1.45 x 10(10)s2 x g(-1), but the bioleached sludge was still difficult to be dewatered. After adjusting the bioleached sludge pH to 6, PAC and PAM were used to enhance conditioning of the bioleached sludge. The results indicated that the optimal dosage was 200 mg x L(-1) for PAC or 50 mg x L(-1) for PAM when single chemical was used. When PAC and PAM were dually used, the optimal dosages of PAC and PAM were 100 mg x L(-1) and 25 mg x L(-1), respectively; SRF and moisture of sludge cake reduced to 2.02 x 10(8) s2 x g(-1) and 74.81%, respectively, showing good dewaterability of the treated sludge. Compared with the single use of PAC and PAM, the dual use of PAC and PAM showed the advantages of lower cost and better conditioning effect.
采用生物浸出 - 双加聚合氯化铝(PAC)和聚丙烯酰胺(PAM)的方法对污水污泥进行调理。结果表明,在固定硫粉用量为3 g·L⁻¹的情况下,添加FeSO₄·7H₂O能显著提高生物浸出率;当FeSO₄·7H₂O用量为8 g·L⁻¹时,生物浸出持续1.5 d可使污泥pH降至2以下。生物浸出显著改善了污泥的脱水性能,比过滤阻力(SRF)从6.45×10¹⁰s²·g⁻¹降低77.52%至1.45×10¹⁰s²·g⁻¹,但生物浸出后的污泥仍难以脱水。将生物浸出后的污泥pH调至6后,使用PAC和PAM增强对生物浸出污泥的调理。结果表明,单独使用化学药剂时,PAC的最佳用量为200 mg·L⁻¹,PAM的最佳用量为50 mg·L⁻¹。当同时使用PAC和PAM时,PAC和PAM的最佳用量分别为100 mg·L⁻¹和25 mg·L⁻¹;污泥饼的SRF和含水率分别降至2.02×10⁸s²·g⁻¹和74.81%,表明处理后的污泥具有良好的脱水性能。与单独使用PAC和PAM相比,同时使用PAC和PAM具有成本更低、调理效果更好的优点。