Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48 Vass. Constantinou Ave., Athens 116 35, Greece.
Chem Commun (Camb). 2010 Dec 28;46(48):9110-2. doi: 10.1039/c0cc04108d. Epub 2010 Nov 16.
The covalent functionalization of the external wall of C(60)@SWCNT peapods, by in situ generated aryl diazonium salts, assisted by microwave irradiation is reported. Spectroscopic, thermal and microscopy characterization was performed. Electrochemistry revealed the three reversible reductions of encapsulated C(60), however, shifted towards positive potentials when compared with those of intact C(60).
通过原位生成的芳基重氮盐，并辅助微波辐射，实现了 C(60)@SWCNT 豆荚外管壁的共价功能化。对其进行了光谱、热重和显微镜特性分析。电化学结果表明，包埋的 C(60)可发生 3 次可逆还原，但与完整的 C(60)相比，其还原电位向正方向移动。
