Measurements of hydroxyl concentrations and lifetimes in laminar flames using picosecond time-resolved laser-induced fluorescence.

Picosecond time-resolved laser-induced fluorescence (PITLIF) can potentially be used to obtain measurements of minor species concentrations in rapidly fluctuating flames. Previous studies demonstrated this potential for atomic sodium by monitoring the temporal fluorescence signal with both an equivalent-time and a real-time sampling method. In this developmental study, PITLIF is used to determine hydroxyl concentrations in laminar CH(4)-O(2)-N(2) flames by the measurement of both the integrated fluorescence signal and the fluorescence lifetime. The quenching environment can be monitored with real-time sampling, and thus the necessary quenching rate coefficient is obtained in 348 us, which is fast enough for use in many turbulent flows. Fluorescence lifetimes of OH are also measured at different equivalence ratios in laminar flames by the use of the equivalent-time sampling technique. These results compare favorably with predicted lifetimes based on relevant quenching cross sections and calculated species concentrations.