Institut für Organische Chemie und Makromolekulare Chemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstraße 1, 40225 Düsseldorf, Germany.
Beilstein J Org Chem. 2010 Oct 1;6:938-44. doi: 10.3762/bjoc.6.105.
Epoxide-amine oligo-adducts were synthesized via a one-pot microwave assisted heterogeneous catalytic transfer hydrogenation. Accordingly, 4-nitroanisole was reduced under microwave conditions to give 4-aminoanisole which reacted immediately with the diglycidyl ether of bisphenol A in an addition polymerization reaction to yield oligo(amino alcohol)s. The hydroxy groups of the new formed oligomers were used as the initiator for the ring-opening polymerization of ε-caprolactone to produce a graft copolymer.
环氧化物-胺低聚物通过一锅微波辅助非均相催化转移氢化合成。相应地，在微波条件下还原 4-硝基苯甲醚得到 4-氨基苯甲醚，其立即与双酚 A 的二缩水甘油醚在加成聚合反应中反应，生成低聚（氨基醇）。新形成的低聚物的羟基用作 ε-己内酯开环聚合的引发剂，生成接枝共聚物。
