轴向吡啶取代的环糖醇衍生骨架的设计与合成及其对银（I）阳离子的包合作用。
Design and synthesis of a cyclitol-derived scaffold with axial pyridyl appendages and its encapsulation of the silver(I) cation.
机构信息
Département de Chimie Moléculaire (CNRS, UMR 5250, ICMG FR-2607) Université Joseph Fourier, 301 Rue de la Chimie, 38402 Grenoble Cedex, France.
出版信息
Beilstein J Org Chem. 2010 Oct 29;6:1022-4. doi: 10.3762/bjoc.6.115.
Abstract
Conversion of a myo-inositol derivative into a scyllo-inositol-derived scaffold with C₃(v) symmetry bearing three axial pyridyl appendages is presented. This pre-organized hexadentate ligand allows complexation of silver(I). The crystal structure of the complex was established.
摘要
本文报道了将肌醇衍生物转化为具有 C₃(v) 对称的海鞘衍生骨架，其中包含三个轴向吡啶基团。这种预组织的六齿配体允许银（I）的络合。确定了配合物的晶体结构。
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