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海恩斯维尔页岩天然气开发的臭氧影响。

Ozone impacts of natural gas development in the Haynesville Shale.

机构信息

ENVIRON International Corporation, 773 San Marin Drive, Novato, California 94998, United States.

出版信息

Environ Sci Technol. 2010 Dec 15;44(24):9357-63. doi: 10.1021/es1021137. Epub 2010 Nov 18.

DOI:10.1021/es1021137
PMID:21086985
Abstract

The Haynesville Shale is a subsurface rock formation located beneath the Northeast Texas/Northwest Louisiana border near Shreveport. This formation is estimated to contain very large recoverable reserves of natural gas, and during the two years since the drilling of the first highly productive wells in 2008, has been the focus of intensive leasing and exploration activity. The development of natural gas resources within the Haynesville Shale is likely to be economically important but may also generate significant emissions of ozone precursors. Using well production data from state regulatory agencies and a review of the available literature, projections of future year Haynesville Shale natural gas production were derived for 2009-2020 for three scenarios corresponding to limited, moderate, and aggressive development. These production estimates were then used to develop an emission inventory for each of the three scenarios. Photochemical modeling of the year 2012 showed increases in 2012 8-h ozone design values of up to 5 ppb within Northeast Texas and Northwest Louisiana resulting from development in the Haynesville Shale. Ozone increases due to Haynesville Shale emissions can affect regions outside Northeast Texas and Northwest Louisiana due to ozone transport. This study evaluates only near-term ozone impacts, but the emission inventory projections indicate that Haynesville emissions may be expected to increase through 2020.

摘要

海恩斯维尔页岩位于美国东北部得克萨斯州/西北部路易斯安那州边界附近的什里夫波特地下。据估计,该地层蕴藏着大量可回收的天然气储量,自 2008 年首次钻探出高产井以来的两年中,该地区一直是密集租赁和勘探活动的焦点。海恩斯维尔页岩内天然气资源的开发可能具有重要的经济意义,但也可能产生大量臭氧前体排放。利用州监管机构的井产量数据和对现有文献的审查,对 2009-2020 年三种对应有限、适度和积极开发的情景下未来的海恩斯维尔页岩天然气产量进行了预测。然后,使用这些产量估计值为三种情景中的每一种开发了排放清单。2012 年的光化学模拟显示,由于海恩斯维尔页岩的开发,导致美国东北部得克萨斯州和西北部路易斯安那州的 2012 年 8 小时臭氧设计值增加了 5 个百分点。由于海恩斯维尔页岩排放而导致的臭氧增加可能会影响到得克萨斯州东北部和路易斯安那州西北部以外的地区,因为臭氧会发生传输。本研究仅评估了近期的臭氧影响,但排放清单预测表明,海恩斯维尔的排放量可能会持续到 2020 年。

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