Division of Organic Chemistry, National Chemical Laboratory, Pune411008, India.
J Org Chem. 2010 Dec 17;75(24):8705-8. doi: 10.1021/jo101813z. Epub 2010 Nov 19.
X-ray crystallographic studies of methylene linked Ferrocene-bis(thymine/uracil) conjugates Fc(T:T)(M) and Fc(U:U)(M) reveal base dependent 2-D supramolecular assemblies generated via wobble self-pairing for bis-thymine and reverse wobble self-pairing for bis-uracil conjugates, differing in architecture from the corresponding butylene spacer linked conjugates.
X 射线晶体学研究表明，亚甲基连接的二茂铁-双（胸腺嘧啶/尿嘧啶）缀合物 Fc（T:T）（M）和 Fc（U:U）（M）通过摆动自配对生成碱基依赖性的 2-D 超分子组装体，用于双胸腺嘧啶，而对于双尿嘧啶缀合物则采用反向摆动自配对，其结构与相应的丁烯间隔基连接的缀合物不同。
