Gomes Margarida F Costa, Lopes J N Canongia, Padua A A H
Laboratoire Thermodynamique et Interactions Moléculaires, Université Blaise Pascal, Clermont-Ferrand/CNRS, Aubière, France,
Top Curr Chem. 2010;290:161-83. doi: 10.1007/128_2009_2.
The high degree of organisation in the fluid phase of room-temperature ionic liquids has major consequences on their macroscopic properties, namely on their behaviour as solvents. This nanoscale self-organisation is the result of an interplay between two types of interaction in the liquid phase - Coulomb and van der Waals - that eventually leads to the formation of medium-range structures and the recognition of some ionic liquids as composed of a high-charge density, cohesive network permeated by low-charge density regions.In this chapter, the structure of the ionic liquids will be explored and some of their consequences to the properties of ionic liquids analyzed.
室温离子液体液相中的高度组织性对其宏观性质，即作为溶剂的行为有重大影响。这种纳米级的自组织是液相中两种相互作用——库仑相互作用和范德华相互作用——相互作用的结果，最终导致形成中程结构，并使一些离子液体被认为是由高电荷密度的内聚网络和低电荷密度区域渗透组成的。在本章中，将探讨离子液体的结构，并分析其对离子液体性质的一些影响。
