储氢性能和中子散射研究的 Mg2(dobdc) - 一个具有开放 Mg2+吸附位的金属有机骨架。
Hydrogen storage properties and neutron scattering studies of Mg2(dobdc)--a metal-organic framework with open Mg2+ adsorption sites.
机构信息
Department of Chemistry, University of California, Berkeley, California 94720, USA.
出版信息
Chem Commun (Camb). 2011 Jan 28;47(4):1157-9. doi: 10.1039/c0cc03453c. Epub 2010 Nov 25.
PMID:21109867
Abstract
The hydrogen storage properties of Mg(2)(dobdc) (dobdc(4-) = 2,5-dioxido-1,4-benzenedicarboxylate), a metal-organic framework possessing hexagonal one-dimensional channels decorated with unsaturated Mg(2+) coordination sites, have been examined through low- and high-pressure adsorption experiments, infrared spectroscopy, and neutron scattering studies.
摘要
研究了具有六方一维通道且通道壁上修饰有不饱和 Mg(2+)配位位的金属-有机骨架 Mg(2)(dobdc)（dobdc(4-) = 2,5-二氧代-1,4-苯二甲酸根）的储氢性能，通过低压和高压吸附实验、红外光谱和中子散射研究进行了考察。
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