β-环糊精负载的孤立铜（I）位点：用于噻吩捕获的有效π络合吸附剂。

Isolated Cu(I) sites supported on β-cyclodextrin: an efficient π-complexation adsorbent for thiophene capture.

机构信息

State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China.

出版信息

Chem Commun (Camb). 2011 Jan 14;47(2):650-2. doi: 10.1039/c0cc04587j. Epub 2010 Nov 29.

DOI:10.1039/c0cc04587j

PMID:21116539

Abstract

A novel π-complexation adsorbent is fabricated by grafting Cu(I)-containing molecule precursors onto β-cyclodextrin. The adsorbent provides a molecular-level dispersion of Cu(I), which is particularly beneficial to the adsorptive removal of aromatic sulfur thiophene, and is impossible to be realized through the conventional thermal method.

摘要

一种新型的π络合吸附剂是通过将含 Cu(I) 的分子前体接枝到β-环糊精上制备的。该吸附剂提供了 Cu(I) 的分子级分散，这对于芳香族硫噻吩的吸附去除特别有利，而通过传统的热方法是不可能实现的。