表面活性剂介导水中氧气的再摄取进行绿色需氧氧化：通过质谱测定离散中间体来关联氧气摄取与氧化效率。

Surfactant mediated oxygen reuptake in water for green aerobic oxidation: mass-spectrometric determination of discrete intermediates to correlate oxygen uptake with oxidation efficiency.

机构信息

Department of Medicinal Chemistry, National Institute of Pharmaceutical Education and Research (NIPER), Sector 67, S. A. S. Nagar, Punjab 160 062, India.

出版信息

Chem Commun (Camb). 2011 Feb 14;47(6):1797-9. doi: 10.1039/c0cc03166f. Epub 2010 Dec 3.

DOI:10.1039/c0cc03166f

PMID:21127798

Abstract

A novel strategy of catalytic green aerobic oxidation by surfactant-mediated oxygen reuptake in water offers a new dimension to the applications of surfactants to look beyond as solubility aids and a conceptual advancement in understanding the role of surfactants in aquatic organic reactions through mass spectrometry guided identification of discrete intermediates.

摘要

表面活性剂介导的水中氧气再摄取的新型催化绿色有氧氧化策略，为表面活性剂的应用提供了新的维度，超越了作为溶解度助剂的作用，并通过质谱引导的离散中间体的鉴定，在理解表面活性剂在水有机反应中的作用方面取得了概念上的进展。