Mori Hideharu, Müller Axel H E
Makromolekulare Chemie II, Bayreuther Institut für Makromolekülforschung and Bayreuther Zentrum für Kolloide und Grenzflächen , Universität Bayreuth, Bayreuth, 95440, Germany.
Top Curr Chem. 2003;228:1-37. doi: 10.1007/b11004.
This review summarizes recent advances in the synthesis and characterization of hyperbranched (meth)acrylates. We will focus on self-condensing vinyl (co)polymerization as an effective method for the synthesis of hyperbranched polymers. Molecular parameters of hyperbranched polymers obtained by self-condensing vinyl (co)polymerization are discussed from a theoretical point of view. Solution properties and melt properties of the resulting hyperbranched poly(meth)acrylates and poly(acrylic acid)s are reviewed. A novel synthetic concept for preparing hyperbranched polymer brushes on planar surfaces and nanoparticles is also described.
本综述总结了超支化（甲基）丙烯酸酯合成与表征方面的最新进展。我们将重点关注自缩合乙烯基（共）聚合，这是一种合成超支化聚合物的有效方法。从理论角度讨论了通过自缩合乙烯基（共）聚合得到的超支化聚合物的分子参数。综述了所得超支化聚（甲基）丙烯酸酯和聚（丙烯酸）的溶液性质和熔体性质。还描述了一种在平面表面和纳米颗粒上制备超支化聚合物刷的新颖合成概念。
