钯催化的 2,5-取代吡咯的 C-H 芳基化反应。
Palladium-catalyzed C-H arylation of 2,5-substituted pyrroles.
机构信息
University of Michigan, Department of Chemistry, 930 North University Avenue, Ann Arbor, Michigan 48019, USA.
出版信息
Org Lett. 2011 Jan 21;13(2):288-91. doi: 10.1021/ol102734g. Epub 2010 Dec 8.
PMID:21141808
Abstract
The palladium-catalyzed direct arylation of 2,5-substituted pyrrole derivatives with diaryliodonium salts to generate tri-, tetra-, and penta-substituted pyrrole products is described. The scope and limitations of these transformations are also reported.
摘要
钯催化的 2,5-取代吡咯衍生物与二芳基碘鎓盐的直接芳基化反应，生成三、四、五取代吡咯产物，本文对此进行了描述。同时还报道了这些转化的适用范围和局限性。
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