Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, Kurokami, Kumamoto, Japan.
Dalton Trans. 2011 Mar 14;40(10):2167-9. doi: 10.1039/c0dt01052a. Epub 2010 Dec 9.
The cobalt(II) compounds with long alkyl chains, Co(C12-terpy)(2)(2)·EtOH·0.5H(2)O(1·EtOH·0.5H(2)O) and Co(C12-terpy)(2)(2) (1) was synthesized and characterized. The compound 1·EtOH·0.5H(2)O exhibits a "re-entrant spin crossover". The compound 1 exhibits the reentrant spin crossover and multi phase transitions with a wide thermal hysteresis loop.
合成并表征了具有长烷基链的钴（II）配合物Co(C12-terpy)(2)(2)·EtOH·0.5H(2)O(1·EtOH·0.5H(2)O)和Co(C12-terpy)(2)(2)(1)。化合物 1·EtOH·0.5H(2)O 表现出“再入自旋交叉”。化合物 1 表现出再入自旋交叉和多相转变，具有宽的热滞回线。
