控制客体在分子笼内的旋转。
Controlling the rotation of a complexed guest within a molecular cage.
机构信息
Department of Chemistry, National Taiwan University, Taipei, Taiwan, ROC.
出版信息
Dalton Trans. 2011 Mar 14;40(10):2163-6. doi: 10.1039/c0dt00375a. Epub 2010 Dec 10.
PMID:21152571
Abstract
A molecular cage-based complex, in which the complexed guest changes its binding geometry with respect to the macrocyclic host upon the addition and removal of K(+) ions, is reported.
摘要
报道了一种基于分子笼的配合物，其中配合物客体在添加和去除 K(+) 离子时相对于大环主体改变其结合几何形状。
相似文献
1
Controlling the rotation of a complexed guest within a molecular cage.控制客体在分子笼内的旋转。
Dalton Trans. 2011 Mar 14;40(10):2163-6. doi: 10.1039/c0dt00375a. Epub 2010 Dec 10.
2
Host-guest chemistry with bi- and tetra-nuclear macrocyclic metallasupramolecules.主体-客体化学与双和四核大环金属超分子。
Chem Commun (Camb). 2010 Oct 7;46(37):6879-90. doi: 10.1039/c0cc00770f. Epub 2010 Aug 23.
3
Selective templated complexation of a cylindrical macrotricyclic host with neutral guests: three cation-controlled switchable processes.圆柱形大环三环主体与中性客体的选择性模板络合：三种阳离子控制的可切换过程。
J Org Chem. 2007 Sep 14;72(19):7287-93. doi: 10.1021/jo071195x. Epub 2007 Aug 22.
4
A cyclopeptide-derived molecular cage for sulfate ions that closes with a click.一种由环肽衍生而来的分子笼，可以通过点击反应关闭以容纳硫酸根离子。
Chemistry. 2010 Jun 25;16(24):7241-55. doi: 10.1002/chem.201000308.
5
Staudinger reaction at in-bridgehead positions of phosphorus macrobicyclic compounds.磷大环化合物桥头位置的施陶丁格反应。
Chemistry. 2004 Aug 20;10(16):4011-6. doi: 10.1002/chem.200400204.
6
Structure and photochemistry of 18-diazo-1,4,7,10,13,16-hexaoxacyclononadeca-17,19-dione and its sodium and potassium complexes. Control of the ground-state conformation of 2-diazo-1,3-dicarbonyl fragment via host-guest complexation.18-重氮-1,4,7,10,13,16-六氧杂环十九碳-17,19-二酮及其钠和钾配合物的结构与光化学。通过主客体络合控制2-重氮-1,3-二羰基片段的基态构象。
J Org Chem. 2005 Nov 25;70(24):9867-73. doi: 10.1021/jo051594x.
7
The X-ray structure of Salmonella typhimurium uridine nucleoside phosphorylase complexed with 2,2'-anhydrouridine, phosphate and potassium ions at 1.86 A resolution.鼠伤寒沙门氏菌尿苷核苷磷酸化酶与2,2'-脱水尿苷、磷酸和钾离子复合物的X射线晶体结构，分辨率为1.86埃。
Acta Crystallogr D Biol Crystallogr. 2010 Jan;66(Pt 1):51-60. doi: 10.1107/S0907444909044175. Epub 2009 Dec 21.
8
Construction of an interpenetrated structure of macrocycles.大环的贯穿结构的构建。
Chem Commun (Camb). 2010 Aug 21;46(31):5698-700. doi: 10.1039/c0cc01120g. Epub 2010 Jul 1.
9
A molecular balloon: expansion of a molecular gyrotop cage due to rotation of the phenylene rotor.分子气球：苯撑转子旋转导致分子陀螺笼的膨胀。
J Am Chem Soc. 2012 Aug 1;134(30):12458-61. doi: 10.1021/ja305822e. Epub 2012 Jul 19.
10
A convergent coordination chemistry-based approach to dissymmetric macrocyclic cofacial porphyrin complexes.一种基于收敛配位化学的方法合成不对称大环共面卟啉配合物。
Inorg Chem. 2007 Sep 17;46(19):7716-8. doi: 10.1021/ic701424j. Epub 2007 Aug 14.
Zotero 插件