The Department of Chemistry, Yale University, PO Box 208107, New Haven, Connecticut 06520, USA.
Chem Commun (Camb). 2011 Feb 14;47(6):1824-6. doi: 10.1039/c0cc03898a. Epub 2010 Dec 14.
The reactions of PCP supported Ni hydride, methyl and allyl species with CO(2) to generate Ni carboxylates are described. Computational studies suggest that all three reactions follow different pathways.
描述了负载在 PCP 上的 Ni 氢化物、甲基和烯丙基物种与 CO2 的反应,生成了 Ni 羧酸盐。计算研究表明,这三种反应遵循不同的途径。