苯甲酮类化合物、friedolanostane、friedocycloartane 是藤黄属植物树皮和叶子的成分。

Friedolanostane, friedocycloartane and benzophenone constituents of the bark and leaves of Garcinia benthami.

机构信息

Faculty of Chemistry, Ho Chi Minh City University of Science (HCMUS), Ho Chi Minh City, Viet Nam.

出版信息

Phytochemistry. 2011 Feb;72(2-3):290-5. doi: 10.1016/j.phytochem.2010.11.016. Epub 2010 Dec 16.

DOI:10.1016/j.phytochem.2010.11.016

Abstract

Friedolanostanes, (22Z,24E)-3β-acetoxy-9α-hydroxy-17,14-friedolanosta-14,22,24-trien-26-oic acid, (22Z,24E)-3β,9α-dihydroxy-17,14-friedolanosta-14,22,24-trien-26-oic acid, (22Z,24E)-9α-hydroxy-3-oxo-17,14-friedolanosta-14,22,24-trien-26-oic acid, a friedocycloartane, (22Z,24E)-3α-hydroxy-17,13-friedocycloarta-12,22,24-trien-26-oic acid, and a benzophenone, benthaphenone, together with known compounds (22Z,24E)-3α,9α-dihydroxy-17,13-friedolanosta-12,22,24-trien-26-oic acid, methyl (24E)-3α,23-dihydroxy-17,14-friedolanosta-8,14,24-trien-26-oate, glutinol, lupeol, and stigmasterol, were isolated from leaves and bark of Garcinia benthami. Their structures were elucidated using spectroscopic techniques, mainly 1-D and 2-D NMR spectroscopy, and chemical correlations.

摘要

Friedolanostanes、(22Z,24E)-3β-乙酰氧基-9α-羟基-17,14-弗里多兰烷-14,22,24-三烯-26-酸、(22Z,24E)-3β,9α-二羟基-17,14-弗里多兰烷-14,22,24-三烯-26-酸、(22Z,24E)-9α-羟基-3-氧代-17,14-弗里多兰烷-14,22,24-三烯-26-酸、一种 friedocycloartane、(22Z,24E)-3α-羟基-17,13-friedocycloarta-12,22,24-三烯-26-酸和一种苯并二酮 benthaphenone，以及已知化合物(22Z,24E)-3α,9α-二羟基-17,13-弗里多兰烷-12,22,24-三烯-26-酸、甲基(24E)-3α,23-二羟基-17,14-弗里多兰烷-8,14,24-三烯-26-酸、谷甾醇、羽扇豆醇和豆甾醇，从 Garcinia benthami 的叶和树皮中分离得到。它们的结构通过光谱技术，主要是 1-D 和 2-D NMR 光谱和化学相关性来阐明。