• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

增强型非极性聚硅氧烷和离子液体柱系列对多氯联苯的二维气相色谱全分辨率。

Enhanced comprehensive two-dimensional gas chromatographic resolution of polychlorinated biphenyls on a non-polar polysiloxane and an ionic liquid column series.

机构信息

Department of Analytical Chemistry, Faculty of Science, Palacky University, Olomouc, Czech Republic.

出版信息

J Chromatogr A. 2011 Feb 4;1218(5):746-51. doi: 10.1016/j.chroma.2010.12.013. Epub 2010 Dec 14.

DOI:10.1016/j.chroma.2010.12.013
PMID:21185568
Abstract

A total of 196 out of 209 polychlorobiphenyl (PCB) congeners were resolved using GC×GC-TOFMS with a non-polar/ionic liquid column series consisting of poly(50%-n-octyl-50%-methyl)siloxane and (1,12-di(tripropylphosphonium)dodecane bis(trifluoromethansulfonyl)amide) in the first and second dimension, respectively. It has been found that 13 PCB congeners overlap in five doublets (CB12+CB13, CB62+CB75, CB70+CB76, CB97+CB125 and CB153+CB168) and one triplet (CB90+CB101+CB113). All toxic, "dioxin like" congeners were separated with no interferences from any PCB congener. The 109 PCBs present in Aroclor 1242 and the 82 PCBs present in Aroclor 1260 were resolved GC×GC-TOFMS analysis on this column set.

摘要

使用气相色谱-飞行时间质谱联用仪，通过非极性/离子液体柱系列（第一维和第二维分别为聚（50%-正辛基-50%-甲基）硅氧烷和（1,12-双（三丙基膦）十二烷双（三氟甲磺酰基）酰胺）），共解析了 209 种多氯联苯（PCB）同系物中的 196 种。研究发现，有 13 种 PCB 同系物在五个二联体（CB12+CB13、CB62+CB75、CB70+CB76、CB97+CB125 和 CB153+CB168）和一个三联体（CB90+CB101+CB113）中重叠。所有有毒的“二噁英样”同系物都被分离出来，没有任何 PCB 同系物的干扰。在该柱组上，用气相色谱-飞行时间质谱联用仪分析了 Aroclor 1242 中的 109 种 PCB 和 Aroclor 1260 中的 82 种 PCB。

相似文献

1
Enhanced comprehensive two-dimensional gas chromatographic resolution of polychlorinated biphenyls on a non-polar polysiloxane and an ionic liquid column series.增强型非极性聚硅氧烷和离子液体柱系列对多氯联苯的二维气相色谱全分辨率。
J Chromatogr A. 2011 Feb 4;1218(5):746-51. doi: 10.1016/j.chroma.2010.12.013. Epub 2010 Dec 14.
2
Use of a polar ionic liquid as second column for the comprehensive two-dimensional GC separation of PCBs.使用极性离子液体作为第二柱对多氯联苯进行全面二维 GC 分离。
J Chromatogr A. 2010 Sep 10;1217(37):5859-67. doi: 10.1016/j.chroma.2010.07.024. Epub 2010 Jul 21.
3
Gas chromatography of 209 polychlorinated biphenyl congeners on an extremely efficient nonselective capillary column.在一根高效非选择性毛细管柱上对209种多氯联苯同系物进行气相色谱分析。
J Chromatogr A. 2009 Aug 7;1216(32):6043-62. doi: 10.1016/j.chroma.2009.06.049. Epub 2009 Jun 21.
4
Evaluation of ionic liquid gas chromatography stationary phases for the separation of polychlorinated biphenyls.评估离子液体气相色谱固定相用于多氯联苯的分离。
J Chromatogr A. 2018 Jul 20;1559:156-163. doi: 10.1016/j.chroma.2017.12.029. Epub 2017 Dec 12.
5
Evaluation of ionic liquid stationary phases for one dimensional gas chromatography-mass spectrometry and comprehensive two dimensional gas chromatographic analyses of fatty acids in marine biota.评估离子液体固定相在一维气相色谱-质谱联用和海洋生物体内脂肪酸的全面二维气相色谱分析中的应用。
J Chromatogr A. 2011 May 20;1218(20):3056-63. doi: 10.1016/j.chroma.2011.03.011. Epub 2011 Mar 13.
6
Fingerprinting polychlorinated biphenyls in environmental samples using comprehensive two-dimensional gas chromatography with time-of-flight mass spectrometry.使用带有飞行时间质谱的全面二维气相色谱对环境样本中的多氯联苯进行指纹分析。
J Chromatogr A. 2013 Nov 29;1318:276-83. doi: 10.1016/j.chroma.2013.10.016.
7
Enantiomeric separation of chiral polychlorinated biphenyls on beta-cyclodextrin capillary columns by means of heart-cut multidimensional gas chromatography and comprehensive two-dimensional gas chromatography. Application to food samples.通过中心切割多维气相色谱法和全二维气相色谱法在β-环糊精毛细管柱上对手性多氯联苯进行对映体分离。应用于食品样品。
J Sep Sci. 2005 Feb;28(2):163-71. doi: 10.1002/jssc.200401868.
8
Improved separation of the 209 polychlorinated biphenyl congeners using comprehensive two-dimensional gas chromatography-time-of-flight mass spectrometry.使用全二维气相色谱-飞行时间质谱法改进对209种多氯联苯同系物的分离。
J Chromatogr A. 2004 Jun 25;1040(2):227-38. doi: 10.1016/j.chroma.2004.04.003.
9
Congener-specific analysis of non-dioxin-like polychlorinated biphenyls in blood collected from 195 pregnant women in Sapporo City, Japan.对从日本札幌市195名孕妇采集的血液中同类非二噁英类多氯联苯进行的特定同系物分析。
Chemosphere. 2008 Oct;73(6):923-31. doi: 10.1016/j.chemosphere.2008.06.071. Epub 2008 Aug 20.
10
Isotope dilution analysis of polychlorinated biphenyls (PCBs) in transformer oil and global commercial PCB formulations by high resolution gas chromatography-high resolution mass spectrometry.采用高分辨率气相色谱-高分辨率质谱法对变压器油和全球商用多氯联苯（PCB）配方中的多氯联苯进行同位素稀释分析。
Chemosphere. 2006 Jan;62(3):469-84. doi: 10.1016/j.chemosphere.2005.04.034. Epub 2005 Jun 8.

引用本文的文献

1
The Influence of Ionic Liquids on the Effectiveness of Analytical Methods Used in the Monitoring of Human and Veterinary Pharmaceuticals in Biological and Environmental Samples-Trends and Perspectives.离子液体对用于监测生物和环境样品中人类和兽医药品的分析方法的有效性的影响——趋势和展望。
Molecules. 2020 Jan 10;25(2):286. doi: 10.3390/molecules25020286.