• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

{1-[1-(3-羧基-丙酰胺基)乙基]-1',2-双-(二苯基膦基)二茂铁-κP,P'}二氯铂(II) 二氯甲烷1.25溶剂合物

{1-[1-(3-Carboxy-propanamido)eth-yl]-1',2-bis-(diphenyl-phosphino)ferrocene-κP,P'}dichloridoplatinum(II) dichloro-methane 1.25-solvate.

作者信息

Spencer Lara C, Bjelosevic Haris, Darkwa James, Elmroth Sofi K C, Persson Tina

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 12;64(Pt 1):m164-5. doi: 10.1107/S1600536807065105.

DOI:10.1107/S1600536807065105
PMID:21200513
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2915101/
Abstract

The dinuclear title compound, [FePtCl(2)(C(17)H(14)P)(C(23)H(23)NO(3)P)]·1.25CH(2)Cl(2), has a slightly distorted cis-PtCl(2)P(2) square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4 (2)° about Pt. In the crystal structure, the complex forms centrosymmetric dimers via two strong inter-molecular O-H⋯O bonds resulting in R(2) (2)(8) rings. A weak intra-molecular N-H⋯Cl bond leads to an S(8) motif. The solvent is highly disordered and has not been modelled with discrete atoms.

摘要

双核标题化合物[FePtCl₂(C₁₇H₁₄P)(C₂₃H₂₃NO₃P)]·1.25CH₂Cl₂中，Pt原子周围具有略微扭曲的顺式-PtCl₂P₂平面正方形几何构型，二茂铁基膦配体围绕Pt以29.4 (2)°的角度交错排列。在晶体结构中，该配合物通过两个强分子间O—H⋯O键形成中心对称二聚体，产生R₂²(8)环。一个弱分子内N—H⋯Cl键导致形成S(8) motif。溶剂高度无序，未用离散原子进行建模。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83a1/2915101/7fdc3ba02fac/e-64-0m164-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83a1/2915101/90c109c8e3bb/e-64-0m164-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83a1/2915101/7fdc3ba02fac/e-64-0m164-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83a1/2915101/90c109c8e3bb/e-64-0m164-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/83a1/2915101/7fdc3ba02fac/e-64-0m164-fig2.jpg

相似文献

1
{1-[1-(3-Carboxy-propanamido)eth-yl]-1',2-bis-(diphenyl-phosphino)ferrocene-κP,P'}dichloridoplatinum(II) dichloro-methane 1.25-solvate.{1-[1-(3-羧基-丙酰胺基)乙基]-1',2-双-(二苯基膦基)二茂铁-κP,P'}二氯铂(II) 二氯甲烷1.25溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 12;64(Pt 1):m164-5. doi: 10.1107/S1600536807065105.
2
[1,1'-Bis(diphenyl-phosphino)cobalto-cenium-κP,P']dichloridoplatinum(II) hexa-fluorido-phosphate.[1,1'-双（二苯基膦基）钴鎓-κP,P']二氯铂（II）六氟磷酸盐
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 22;65(Pt 8):m960. doi: 10.1107/S1600536809027925.
3
[N,N-Bis(diphenyl-phosphino)propyl-amine-κP,P']dichloridoplatinum(II).[二氯（N,N-双（二苯基膦基）丙基胺-κP,P'）铂（II）]
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 12;66(Pt 1):m51-2. doi: 10.1107/S160053680905301X.
4
Bis[N,N-bis-(diphenyl-phosphan-yl)pentyl-amine-κP,P']platinum(II) bis-(hexa-fluoridophosphate) dichloro-methane disolvate.双[N,N-双-(二苯基膦基)戊基-胺-κP,P']铂(II)双(六氟磷酸酯)二氯甲烷溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 14;66(Pt 8):m922-3. doi: 10.1107/S1600536810025560.
5
[2,2'-Bis(diphenyl-phosphan-yl)-1,1'-binaphthyl-κP,P']chlorido(4-methyl-phenyl-sulfon-yl-κS)palladium(II) dichloro-methane tris-olvate monohydrate.[2,2'-双（二苯基膦基）-1,1'-联萘-κP,P']氯（4-甲基苯磺酰基-κS）钯（II）二氯甲烷三溶剂合物一水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1830. doi: 10.1107/S1600536811049889. Epub 2011 Nov 25.
6
[1,1'-Bis(diphenyl-phosphan-yl)ferrocene-κP,P']dichloridocadmium(II) dichloro-methane disolvate.[1,1'-双（二苯基膦基）二茂铁-κP,P']二氯化镉（II）二氯甲烷溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 17;66(Pt 12):m1586. doi: 10.1107/S1600536810046635.
7
Dichlorido{N-[2-(diphenyl-phosphan-yl)benzyl-idene]-2-(thio-phen-2-yl)ethan-amine-κP,N}platinum(II) dichloro-methane hemisolvate.二氯{N-[2-(二苯基膦基)亚苄基]-2-(噻吩-2-基)乙胺-κP,N}铂(II) 二氯甲烷半溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m116-7. doi: 10.1107/S1600536811056108. Epub 2012 Jan 7.
8
[μ-Bis(di-o-tolyl-phosphan-yl)methane-1:2κP:P']nona-carbonyl-1κC,2κC,3κC-[diphen-yl(phenyl-sulfanylmeth-yl)phosphane-3κP]-triangulo-triruthenium(0) dichloro-methane 0.25-solvate.[μ-双（二邻甲苯基膦基）甲烷-1:2κP:P']九羰基-1κC,2κC,3κC-[二苯基（苯硫基甲基）膦-3κP]-三角-三钌（0）二氯甲烷0.25溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 15;67(Pt 2):m195-6. doi: 10.1107/S160053681100081X.
9
Bis{[μ-bis-(diphenyl-phosphino)methane-1:2κP:P']nona-carbonyl-1κC,2κC,3κC-[tris-(4-methoxy-phen-yl)arsine-3κAs]-triangulo-triruthenium(0)} dichloro-methane solvate.双{[μ - 双 -（二苯基膦基）甲烷 - 1:2κP:P']九羰基 - 1κC,2κC,3κC - [三 -（4 - 甲氧基苯基）砷 - 3κAs] - 三角 - 三钌（0）}二氯甲烷溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 9;66(Pt 1):m30-1. doi: 10.1107/S1600536809052088.
10
cis-Bis(benzyl-diphenyl-phosphane-κP)dichloridoplatinum(II) dichloro-methane sesquisolvate.顺式双（苄基二苯基膦-κP）二氯铂（II）二氯甲烷倍半溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1800. doi: 10.1107/S1600536811049269. Epub 2011 Nov 23.

本文引用的文献

1
Bioorganometallic chemistry of ferrocene.二茂铁的生物有机金属化学
Chem Rev. 2004 Dec;104(12):5931-85. doi: 10.1021/cr0101510.
2
Synthesis, biochemical properties and molecular modelling studies of organometallic specific estrogen receptor modulators (SERMs), the ferrocifens and hydroxyferrocifens: evidence for an antiproliferative effect of hydroxyferrocifens on both hormone-dependent and hormone-independent breast cancer cell lines.有机金属特异性雌激素受体调节剂（SERM）、二茂铁雌酚和羟基二茂铁雌酚的合成、生化特性及分子模拟研究：羟基二茂铁雌酚对激素依赖性和激素非依赖性乳腺癌细胞系具有抗增殖作用的证据
Chemistry. 2003 Nov 7;9(21):5223-36. doi: 10.1002/chem.200305024.
3
The Cambridge Structural Database: a quarter of a million crystal structures and rising.
剑桥结构数据库：拥有二十五万个晶体结构且数量不断增加。
Acta Crystallogr B. 2002 Jun;58(Pt 3 Pt 1):380-8. doi: 10.1107/s0108768102003890. Epub 2002 May 29.