Spencer Lara C, Bjelosevic Haris, Darkwa James, Elmroth Sofi K C, Persson Tina
Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 12;64(Pt 1):m164-5. doi: 10.1107/S1600536807065105.
The dinuclear title compound, [FePtCl(2)(C(17)H(14)P)(C(23)H(23)NO(3)P)]·1.25CH(2)Cl(2), has a slightly distorted cis-PtCl(2)P(2) square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4 (2)° about Pt. In the crystal structure, the complex forms centrosymmetric dimers via two strong inter-molecular O-H⋯O bonds resulting in R(2) (2)(8) rings. A weak intra-molecular N-H⋯Cl bond leads to an S(8) motif. The solvent is highly disordered and has not been modelled with discrete atoms.
双核标题化合物[FePtCl₂(C₁₇H₁₄P)(C₂₃H₂₃NO₃P)]·1.25CH₂Cl₂中,Pt原子周围具有略微扭曲的顺式-PtCl₂P₂平面正方形几何构型,二茂铁基膦配体围绕Pt以29.4 (2)°的角度交错排列。在晶体结构中,该配合物通过两个强分子间O—H⋯O键形成中心对称二聚体,产生R₂²(8)环。一个弱分子内N—H⋯Cl键导致形成S(8) motif。溶剂高度无序,未用离散原子进行建模。