• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

五水合四[μ-3-(3-吡啶基)丙烯酸根-κO:O']双{(1,10-菲咯啉-κN,N')[3-(3-吡啶基)丙烯酸根-κO,O']铕(III)}

Tetrakis[μ-3-(3-pyridyl)acrylato-κO:O']bis{(1,10-phenanthroline-κN,N')[3-(3-pyridyl)acrylato-κO,O']europium(III)} pentahydrate.

作者信息

Liu Chong-Bo, Wen Hui-Liang, Deng Fang, Zuo Jun-Hui

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 18;64(Pt 1):m201. doi: 10.1107/S1600536807066263.

DOI:10.1107/S1600536807066263
PMID:21200549
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2915131/
Abstract

The europium(III) ion in the title compound, [Eu(2)(C(8)H(6)NO(2))(6)(C(12)H(8)N(2))(2)]·5H(2)O, is coordinated by seven carboxyl-ate O atoms and two N atoms from one phenanthroline mol-ecule. The carboxyl-ate groups of 3-(3-pyrid-yl)acrylate link pairs of europium(III) ions, forming centrosymmetric dinuclear units, which further assemble into a sheet parallel to the (001) plane through hydrogen-bonding inter-actions involving the uncoordinated water mol-ecules. One water molecule is disordered.

摘要

标题化合物[Eu₂(C₈H₆NO₂)₆(C₁₂H₈N₂)₂]·5H₂O中的铕(III)离子由七个羧酸根O原子和来自一个邻菲罗啉分子的两个N原子配位。3-(3-吡啶基)丙烯酸的羧酸根基团连接铕(III)离子对，形成中心对称的双核单元，这些单元通过涉及未配位水分子的氢键相互作用进一步组装成平行于(001)平面的片层。一个水分子无序。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff96/2915131/92eeba09f55d/e-64-0m201-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff96/2915131/92eeba09f55d/e-64-0m201-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff96/2915131/92eeba09f55d/e-64-0m201-fig1.jpg

相似文献

1
Tetrakis[μ-3-(3-pyridyl)acrylato-κO:O']bis{(1,10-phenanthroline-κN,N')[3-(3-pyridyl)acrylato-κO,O']europium(III)} pentahydrate.五水合四[μ-3-(3-吡啶基)丙烯酸根-κO:O']双{(1,10-菲咯啉-κN,N')[3-(3-吡啶基)丙烯酸根-κO,O']铕(III)}
Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 18;64(Pt 1):m201. doi: 10.1107/S1600536807066263.
2
Tetra-μ-acetato-κO:O';κO,O':O;κO:O,O'-bis-[(acetato-κO,O')(1,10-phenanthroline-κN,N')europium(III)].四-μ-乙酸根-κO:O';κO,O':O;κO:O,O'-双-[(乙酸根-κO,O')(1,10-菲咯啉-κN,N')铕(III)]
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 13;66(Pt 12):m1565. doi: 10.1107/S1600536810046131.
3
Poly[[μ(3)-3-(3-pyrid-yl)acrylato-κN:O:O'][μ(2)-3-(3-pyrid-yl)acrylato-κO,O':O][μ(2)-3-(3-pyrid-yl)acrylato-κO:O')]gadolinium(III)].聚[[μ(3)-3-(3-吡啶基)丙烯酸根-κN:O:O'][μ(2)-3-(3-吡啶基)丙烯酸根-κO,O':O][μ(2)-3-(3-吡啶基)丙烯酸根-κO:O']钆(III)]
Acta Crystallogr Sect E Struct Rep Online. 2008 May 3;64(Pt 6):m766-7. doi: 10.1107/S1600536808012270.
4
Tetra-μ-acetato-κO:O';κO,O':O';κO:O,O'-bis-[(acetato-κO,O')(1,10-phenanthroline-κN,N')europium(III)].四-μ-乙酸根-κO:O';κO,O':O';κO:O,O'-双-[(乙酸根-κO,O')(1,10-菲咯啉-κN,N')铕(III)]
Acta Crystallogr Sect E Struct Rep Online. 2010 May 8;66(Pt 6):m606. doi: 10.1107/S1600536810015680.
5
Tetra-kis(μ(2)-2-phen-oxy-propionato)-κO,O':O';κO:O,O';κO:O'-bis-[(1,10-phenanthroline-κN,N')(2-phen-oxy-propionato-κO,O')cerium(III)].四-双（μ(2)-2-苯氧基丙酸根）-κO,O':O';κO:O,O';κO:O'-双-[(1,10-菲咯啉-κN,N')(2-苯氧基丙酸根-κO,O')铈(III)]
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1359-60. doi: 10.1107/S1600536811036129. Epub 2011 Sep 14.
6
Bis(μ-2-hydroxy-benozato)-κO,O':O';κO:O,O'-bis-[(2-hydroxy-benozato-κO,O')(1,10-phenanthroline-κN,N')cadmium(II)].双（μ-2-羟基苯甲酸根）-κO,O':O';κO:O,O'-双-[(2-羟基苯甲酸根-κO,O')(1,10-菲咯啉-κN,N')镉(II)]
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 25;64(Pt 11):m1458. doi: 10.1107/S1600536808033886.
7
catena-Poly[[[diacrylato-κO,O'-neodymium(III)]-di-μ-acrylato-κO,O':O';κO:O,O'-[triaqua-neodymium(III)]-di-μ-acrylato-κO,O':O';κO:O,O'] trihydrate].链状聚[[[二丙烯酸根合-κO,O'-钕(III)]-二-μ-丙烯酸根合-κO,O':O';κO:O,O'-[三水合钕(III)]-二-μ-丙烯酸根合-κO,O':O';κO:O,O'] 三水合物]
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 8;64(Pt 12):m1492-3. doi: 10.1107/S1600536808026354.
8
Tetra-kis(μ-2-phen-oxy-propionato)-κO,O':O';κO:O,O',κO:O'-bis-[(1,10-phenanthroline-κN,N')(2-phen-oxy-propionato-κO,O')dysprosium(III)].四（μ-2-苯氧基丙酸根）-κO，O'：O'；κO：O，O'，κO：O'-双[（1,10-菲咯啉-κN，N'）（2-苯氧基丙酸根-κO，O'）镝（III）]
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1320. doi: 10.1107/S1600536811034696. Epub 2011 Aug 31.
9
Tetra-kis(μ-2-phen-oxy-propionato)-κO,O':O';κO:O,O',κO:O'-bis-[(1,10-phenanthroline-κN,N')(2-phen-oxy-propionato-κO,O')praseodymium(III)].四-双（μ-2-苯氧基丙酸根）-κO，O'：O'；κO：O，O'，κO：O'-双-[(1,10-菲咯啉-κN，N')(2-苯氧基丙酸根-κO，O')镨(III)]
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1321. doi: 10.1107/S1600536811034702. Epub 2011 Aug 31.
10
Tetra-kis(μ-2-phen-oxy-propionato)-κO,O':O';κO:O,O';κO:O'-bis-[(1,10-phenanthroline-κN,N')(2-phen-oxy-propionato-κO,O')terbium(III)].四-双（μ-2-苯氧基丙酸根）-κO，O'：O'；κO：O，O'；κO：O'-双-[(1,10-菲咯啉-κN，N')(2-苯氧基丙酸根-κO，O')铽(III)]
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1234. doi: 10.1107/S1600536811032041. Epub 2011 Aug 11.

本文引用的文献

1
Novel coordination polymers and structural systematics in the hydrothermal M,M' trans-3(-3-pyridyl)acrylic acid system.水热条件下M、M'反式-3-（3-吡啶基）丙烯酸体系中的新型配位聚合物及结构系统学
Dalton Trans. 2005 Aug 21(16):2788-92. doi: 10.1039/b504862a. Epub 2005 Jul 14.