[二氯双（4-氯苄基）乙二胺锌（II）]
[N,N'-Bis(4-chloro-benz-yl)ethane-1,2-diamine]dichloridozinc(II).
作者信息
Yang Shu-Ping, Han Li-Jun, Wang Da-Qi, Xia Hai-Tao
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 6;64(Pt 1):m62. doi: 10.1107/S1600536807063088.
In the title complex, [ZnCl(2)(C(16)H(18)Cl(2)N(2))], the asymmetric unit contains one mol-ecule and two half-mol-ecules, which have similar geometric parameters; in the latter two molecules each Zn atom lies on a twofold rotation axis. The environment about each Zn(II) atom is distorted tetra-hedral with coordination of two terminal Cl atoms and two N atoms of the N,N'-bis-(4-chloro-benz-yl)ethane-1,2-diamine ligand. Four N-H⋯Cl hydrogen bonds link the mol-ecules into a chain of R(2) (2)(8) rings in the [001] direction.
在标题配合物[ZnCl₂(C₁₆H₁₈Cl₂N₂)]中，不对称单元包含一个分子和两个半分子，它们具有相似的几何参数；在后两个分子中，每个锌原子位于一个二重旋转轴上。每个Zn(II)原子周围的环境呈扭曲的四面体构型，与两个末端氯原子以及N,N'-双(4-氯苄基)乙烷-1,2-二胺配体的两个氮原子配位。四个N-H⋯Cl氢键将分子沿[001]方向连接成R₂²(8)环链。
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