Sudha D, Chinnakali K, Jayagobi M, Raghunathan R, Fun Hoong-Kun
Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 6;64(Pt 1):o134. doi: 10.1107/S1600536807063222.
In the title compound, C(26)H(27)BrN(2)O(2)S, the pyrrolidine ring adopts a twist conformation, while the tetra-hydro-pyridine ring is in a half-chair conformation. The two rings are trans-fused. The dihedral angle between the phenyl ring and the sulfonyl-bound benzene ring is 22.83 (7)°. N-H⋯O hydrogen bonds link the mol-ecules into a chain along the b axis, and the chains are cross-linked into a three-dimensional network by a C-H⋯π inter-action and a weak π-π inter-action between the sulfonyl-bound benzene rings; the centroid-centroid distance is 3.6957 (8) Å.
在标题化合物C(26)H(27)BrN(2)O(2)S中，吡咯烷环呈扭曲构象，而四氢吡啶环处于半椅式构象。这两个环为反式稠合。苯环与磺酰基连接的苯环之间的二面角为22.83 (7)°。N - H⋯O氢键将分子沿b轴连接成链，这些链通过C - H⋯π相互作用以及磺酰基连接的苯环之间的弱π - π相互作用交联成三维网络；质心间距为3.6957 (8) Å。
