Ashmore Jason, Bishop Roger, Craig Donald C, Scudder Marcia L
School of Chemistry, University of New South Wales, Sydney, Australia 2052.
Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 6;64(Pt 1):o48. doi: 10.1107/S1600536807061235.
The racemic title compound, C(27)H(26)N(2)O(4), crystallizes with its central carbon bridge on a twofold axis. It forms parallel chains of mol-ecules utilizing aryl offset face-face inter-actions with an interplanar distance of about 3.5 Å. These chains associate further by means of pairs of O-CH(2)-H⋯π (with H-ring distances ranging from 2.69 to 2.95 Å) and O-CH(2)-H⋯N motifs. The meth-oxy groups in this structure are coplanar with the aromatic rings to which they are attached. This is recognized as being common behaviour amongst aromatic meth-oxy compounds.
外消旋标题化合物C(27)H(26)N(2)O(4),其中心碳桥在一个二重轴上结晶。它利用芳基错开的面对面相互作用形成分子的平行链,面间距约为3.5 Å。这些链通过O-CH(2)-H⋯π对(H-环距离范围为2.69至2.95 Å)和O-CH(2)-H⋯N基序进一步缔合。该结构中的甲氧基与它们所连接的芳环共面。这被认为是芳族甲氧基化合物中的常见行为。