双（二乙三胺-κN,N',N''）镍（II）双（1,2-二氰基乙烯-1,2-二硫醇合-κS,S'）镍（II）
Bis(diethyl-enetriamine-κN,N',N'')nickel(II) bis-(1,2-dicyanoethene-1,2-dithiolato-κS,S')nickel(II).
作者信息
Zhang Dao-Peng, Wang Hai-Long, Zhang Li-Fang, Ni Zhong-Hai
机构信息
School of Chemistry & Chemical Technology, Shandong University, Jinan 250100, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 13;64(Pt 10):m1264-5. doi: 10.1107/S1600536808028663.
The title compound, [Ni(C(4)H(13)N(3))(2)][Ni(C(4)N(2)S(2))(2)], has been synthesized by the reaction of Ni(ClO(4))(2)·6H(2)O, diethyl-enetriamine (deta) and Na(2)[Ni(mnt)(2)] [mnt = maleonitrile-dithiol-ate(2-)] in methanol. The structure is composed of a Ni(deta)(2) cation and a Ni(mnt)(2) anion. The coordination geometry of the Ni(II) ion in the cation is slightly distorted octa-hedral, defined by six N atoms from two deta ligands, while the Ni(II) ion in the anion is four-coordinated by four S atoms from two mnt ligands in a slightly distorted square-planar geometry. The cations and anions are connected by N-H⋯N hydrogen bonds.
标题化合物[Ni(C₄H₁₃N₃)₂][Ni(C₄N₂S₂)₂]是通过Ni(ClO₄)₂·6H₂O、二乙三胺（deta）和Na₂[Ni(mnt)₂] [mnt = 马来腈二硫醇盐(2-)]在甲醇中反应合成的。该结构由[Ni(deta)₂]²⁺阳离子和[Ni(mnt)₂]²⁻阴离子组成。阳离子中Ni(II)离子的配位几何构型为稍有畸变的八面体，由来自两个deta配体的六个N原子界定，而阴离子中Ni(II)离子由来自两个mnt配体的四个S原子以稍有畸变的平面正方形几何构型进行四配位。阳离子和阴离子通过N-H⋯N氢键相连。
Zotero 插件