Pan Chen, Cai Bin, Pei Wen-Bo
Department of Applied Chemistry, College of Science, Nanjing University of Technology, Nanjing 210009, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m730. doi: 10.1107/S160053681101645X. Epub 2011 May 7.
The asymmetric unit of the title complex, (C(6)H(13)N(4))(2)[Ni(C(4)N(2)S(2))(2)], comprises one 1-azonia-3,5,7-triaza-tricyclo-[3.3.1.1(3,7)]decane cation and one half of an Ni(mnt)(2) (mnt(2-) is maleonitrile-dithiol-ate or 1,2-dicyano-ethene-1,2-dithiol-ate) dianion. The Ni(2+) ion is located on a center of inversion and is coordinated by four S atoms from two mnt(2-) ligands in a square-planar coordination mode. Inter-molecular N-H⋯N hydrogen-bond inter-actions link one anion and two cations in the crystal structure.
标题配合物(C₆H₁₃N₄)₂[Ni(C₄N₂S₂)₂]的不对称单元包含一个1-氮杂-3,5,7-三氮杂三环-[3.3.1.1(3,7)]癸烷阳离子和一个[Ni(mnt)₂]²⁻（mnt²⁻为马来腈二硫醇盐或1,2-二氰基乙烯-1,2-二硫醇盐）二价阴离子的一半。Ni²⁺离子位于对称中心，通过来自两个mnt²⁻配体的四个S原子以平面正方形配位模式配位。分子间N-H⋯N氢键相互作用在晶体结构中将一个阴离子和两个阳离子连接起来。
Zotero 插件