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聚[二水合双[μ(2)-2,4-(二氯苯氧基)乙酸根-κO:O']铁(II)]

Poly[diaqua-bis[μ(2)-2,4-(dichloro-phenoxy)-acetato-κO:O']iron(II)].

作者信息

Pan Wei-Bo, Xu Xiao-Hong, Huang Xiao-Hui, Zeng Rong-Hua

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 20;64(Pt 10):m1287. doi: 10.1107/S1600536808029279.

DOI:10.1107/S1600536808029279
PMID:21201032
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2959489/
Abstract

In the title compound, Fe(C(8)H(5)Cl(2)O(3))(2)(H(2)O)(2), the Fe(II) atom is located on an inversion center. It is coordinated by four O atoms from four 2,4-dichloro-phenoxy-acetate ligands and two water mol-ecules, displaying a distorted octa-hedral geometry. The carboxyl-ate groups of the 2,4-dichloro-phenoxy-acetate ligands link the Fe atoms, forming a polymeric layered network in the bc plane. Intra-layer O-H⋯O hydrogen bonds enhance the stability of the two-dimensional network.

摘要

在标题化合物[Fe(C₈H₅Cl₂O₃)₂(H₂O)₂]ₙ中，Fe(II)原子位于一个对称中心上。它由来自四个2,4 - 二氯苯氧基乙酸配体的四个O原子和两个水分子配位，呈现出扭曲的八面体几何构型。2,4 - 二氯苯氧基乙酸配体的羧酸根基团连接Fe原子，在bc平面上形成一个聚合物层状网络。层内O - H⋯O氢键增强了二维网络的稳定性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd2b/2959489/a1af595959e4/e-64-m1287-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd2b/2959489/aef13c7113e9/e-64-m1287-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd2b/2959489/a1af595959e4/e-64-m1287-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd2b/2959489/aef13c7113e9/e-64-m1287-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd2b/2959489/a1af595959e4/e-64-m1287-fig2.jpg

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本文引用的文献

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Modular chemistry: secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks.
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