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Triphenyl-bis(2,4,5-trifluoro-3-methoxy-benzoato)anti-mony(V).

作者信息

Wen Liyuan, Yin Handong, Quan Li, Wang Daqi

机构信息

College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 20;64(Pt 10):m1303. doi: 10.1107/S1600536808029656.

Abstract

In the title compound, [Sb(C(6)H(5))(3)(C(8)H(4)F(3)O(3))(2)], the Sb atom lies on an inversion centre and exhibits a trigonal bipyramidal geometry with the axial positions occupied by the O atoms of two carboxyl-ate groups and the equatorial positions occupied by C atoms of the phenyl groups. Intra-molecular C-H⋯O hydrogen bonds stabilize the mol-ecular conformation. In the crystal structure, mol-ecules are connected by inter-molecular C-H⋯O hydrogen-bonding inter-actions, forming a layer structure parallel to (01).

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/055e/2959366/1591fcd06e52/e-64-m1303-fig1.jpg

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