Chanawanno Kullapa, Chantrapromma Suchada, Fun Hoong-Kun
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 6;64(Pt 10):o1882-3. doi: 10.1107/S1600536808027724.
In the title compound, C(14)H(13)ClN(+)·I(-)·H(2)O, the cation is nearly planar and exists in an E configuration; the dihedral angle between the pyridinium and benzene rings is 0.98 (17)°. The cations stack in an anti-parallel manner along the a axis through two π-π inter-actions between the pyridinium and benzene rings [centroid-centroid distances 3.569 (2) and 3.6818 (13) Å, respectively]. The cation, anion and water mol-ecule are linked into a chain along the a axis by weak C-H⋯O and C-H⋯I inter-actions together with O-H⋯I hydrogen bonds and the chains are further connected into a three-dimensional network.
在标题化合物C₁₄H₁₃ClN⁺·I⁻·H₂O中,阳离子近乎平面,呈E构型;吡啶鎓环与苯环之间的二面角为0.98 (17)°。阳离子沿a轴以反平行方式堆积,通过吡啶鎓环与苯环之间的两个π-π相互作用[质心-质心距离分别为3.569 (2) 和3.6818 (13) Å]。阳离子、阴离子和水分子通过弱C-H⋯O和C-H⋯I相互作用以及O-H⋯I氢键沿a轴连接成链,这些链进一步连接成三维网络。