Fun Hoong-Kun, Chanawanno Kullapa, Chantrapromma Suchada
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 18;65(Pt 8):o1934-5. doi: 10.1107/S1600536809027810.
In the title compound, C(14)H(14)N(+)·I(-), the cation exists in an E configuration with respect to the ethenyl bond and is slightly twisted, the inter-planar angle between the pyridinium and phenyl rings of the cation being 4.8 (2)°. In the crystal packing, the cations are stacked in an anti-parallel fashion along the a axis by a π-π inter-action involving both pyridinium and phenyl rings; the centroid-centroid distance is 3.542 (3) Å. Each iodide ion is sandwiched between two cations. The cations and iodide anions are linked together by weak C-H⋯I inter-actions, giving rise to ladder-like ribbons along the a axis.
在标题化合物C₁₄H₁₄N⁺·I⁻中,阳离子相对于乙烯基键呈E构型且略有扭曲,阳离子的吡啶鎓环和苯环之间的面间角为4.8 (2)°。在晶体堆积中,阳离子通过涉及吡啶鎓环和苯环的π-π相互作用沿a轴以反平行方式堆积;质心间距为3.542 (3) Å。每个碘离子夹在两个阳离子之间。阳离子和碘阴离子通过弱C-H⋯I相互作用连接在一起,沿a轴形成梯状带。