[2,6-双(5-氯嘧啶-2-基-κN)吡啶-κN](2,2':6',2''-三联吡啶-κN,N',N'')钌(II)双(六氟磷酸酯)乙腈溶剂化物
[2,6-Bis(5-chloro-pyrimidin-2-yl-κN)pyri-dine-κN](2,2':6',2''-terpyridine-κN,N',N'')ruthenium(II) bis-(hexa-fluoridophosphate) acetonitrile disolvate.
作者信息
Medlycott Elaine A, Wang Jianhua, Hanan Garry S
机构信息
Département de Chimie, Université de Montréal, CP 6128, Succ. Centre-ville, Montréal, Québec, Canada H3C 3J7.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 9;64(Pt 2):m326. doi: 10.1107/S1600536807068602.
In the title compound, Ru(C(13)H(7)Cl(2)N(5))(C(15)H(11)N(3))(2)·2CH(3)CN, the Ru(II) atom is coordinated in a distorted octa-hedral geometry by a tridentate 2,2':6',2''-terpyridine ligand and a tridentate 2,6-bis-(5-chloro-pyrimidin-2-yl)pyridine ligand. Least-squares mean-plane distortions of only 1.72 (2) and 2.91 (2)° of the pyrimidyl rings with respect to the central pyridine are observed for the bis-(pyrimid-yl)pyridine-based tridentate ligand, while the distal pyridyl rings of terpyridine twist by 13.43 (7) and 4.68 (9)° away from the central pyridine ring.
在标题化合物Ru(C₁₃H₇Cl₂N₅)(C₁₅H₁₁N₃)₂·2CH₃CN中，Ru(II)原子由一个三齿的2,2':6',2''-三联吡啶配体和一个三齿的2,6-双-(5-氯嘧啶-2-基)吡啶配体以扭曲的八面体几何构型配位。对于基于双-(嘧啶基)吡啶的三齿配体，观察到嘧啶环相对于中心吡啶的最小二乘平均平面扭曲仅为1.72 (2)°和2.91 (2)°，而三联吡啶的远端吡啶环相对于中心吡啶环扭转了13.43 (7)°和4.68 (9)°。
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