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N,N'-{[双（三氟甲基）亚甲基]二对亚苯基}二邻苯二甲酰亚胺

N,N'-{[Bis(trifluoro-meth-yl)methyl-ene]di-p-phenyl-ene}diphthalimide.

作者信息

Li Yitao, Wang Zhiguo

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 9;64(Pt 2):o388. doi: 10.1107/S1600536807068249.

DOI:10.1107/S1600536807068249
PMID:21201418
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2960178/
Abstract

The molecule of the title compound, C(31)H(16)F(6)N(2)O(4), consists of two phthalimide units linked by a [bis-(trifluoro-meth-yl)methyl-ene]di-p-phenyl-ene bridge, with the two halves of the mol-ecule related to each other by a twofold rotation axis. The dihedral angle between the planes of the two central benzene rings is 70.5 (3)°. The terminal isoindole groups are approximately planar, with a maximum r.m.s. deviation of 0.006 Å from the mean plane, and they form dihedral angles of 46.03 (3)° to the attached benzene rings. Inter-molecular C-H⋯O hydrogen bonds link neighboring mol-ecules into chains along the c axis.

摘要

标题化合物C(31)H(16)F(6)N(2)O(4)的分子由两个邻苯二甲酰亚胺单元通过一个[双（三氟甲基）亚甲基]二对亚苯基桥连接而成，分子的两半通过一个二重旋转轴相互关联。两个中心苯环平面之间的二面角为70.5 (3)°。末端异吲哚基团近似平面，与平均平面的最大均方根偏差为0.006 Å，它们与相连苯环形成的二面角为46.03 (3)°。分子间的C-H⋯O氢键将相邻分子沿c轴连接成链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7d88/2960178/479aebf9e7a9/e-64-0o388-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7d88/2960178/479aebf9e7a9/e-64-0o388-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7d88/2960178/479aebf9e7a9/e-64-0o388-fig1.jpg

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