Chu Chao-Xia, Zhou Hu, Liu Lang, Yuan Ai-Hua
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 13;64(Pt 9):m1154-5. doi: 10.1107/S1600536808024951.
In the title compound, Co(II)(C(2)H(8)N(2))(3)Mo(V)(CN)(8)·2H(2)O, N-H⋯N and N-H⋯O hydrogen-bonding inter-actions give rise to a three-dimensional network. In the crystal structure, each Mo polyhedron has a square-anti-prismatic shape, while the Co complexes show distorted octa-hedral geometry with an occupancy of 50%. One of the Co atoms resides on a crystallographic inversion centre.
在标题化合物[Co(II)(C₂H₈N₂)₃]₃[Mo(V)(CN)₈]₂·2H₂O中,N—H⋯N和N—H⋯O氢键相互作用形成了三维网络。在晶体结构中,每个钼多面体呈方反棱柱形状,而钴配合物呈现出畸变的八面体几何构型,占有率为50%。其中一个钴原子位于晶体学反演中心上。