• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

4,4-Difluoro-1,3,5,7-tetra-methyl-4-bora-3a,4a-diaza-s-indacene.

作者信息

Xu Hai-Jun

机构信息

Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 6;64(Pt 9):o1672. doi: 10.1107/S1600536808024057.

DOI:10.1107/S1600536808024057
PMID:21201663
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2960520/
Abstract

In the title compound, C(13)H(15)BF(2)N(2), the two pyrrole rings are almost coplanar, with a dihedral angle of 3.08 (10)°. The BF(2) plane is almost perpendicular to the boron-dipyrromethene ring plane, with a dihedral angle of 89.99 (7)°.

摘要

相似文献

1
4,4-Difluoro-1,3,5,7-tetra-methyl-4-bora-3a,4a-diaza-s-indacene.
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 6;64(Pt 9):o1672. doi: 10.1107/S1600536808024057.
2
4,4-Difluoro-1,3,5,7-tetra-methyl-8-penta-fluoro-phenyl-4-bora-3a,4a-diaza-s-indacene.4,4-二氟-1,3,5,7-四甲基-8-五氟苯基-4-硼杂-3a,4a-二氮杂-s-茚
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 6;66(Pt 4):o757. doi: 10.1107/S1600536810003703.
3
Modulation of the spectroscopic property of Bodipy derivates through tuning the molecular configuration.通过调节分子构型来调制 Bodipy 衍生物的光谱性质。
Photochem Photobiol Sci. 2011 Jun;10(6):1030-8. doi: 10.1039/c1pp00001b. Epub 2011 Mar 8.
4
8-Hydroxyquinoline-substituted boron-dipyrromethene compounds: synthesis, structure, and OFF-ON-OFF type of pH-sensing properties.8-羟基喹啉取代的硼二吡咯甲烷化合物:合成、结构及 pH 传感的关-开-关型特性。
J Org Chem. 2011 May 20;76(10):3774-81. doi: 10.1021/jo200050a. Epub 2011 Apr 15.
5
4,4-Difluoro-8-(4-iodo-phen-yl)-1,3,5,7-tetra-methyl-3a-aza-4a-azonia-4-borata-s-indacene.4,4-二氟-8-(4-碘苯基)-1,3,5,7-四甲基-3a-氮杂-4a-氮鎓-4-硼杂-s-茚并环丁二烯
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):o1302. doi: 10.1107/S1600536812004072. Epub 2012 Apr 4.
6
Synthesis and optical properties of 2-(benzo[b]thiophene-3-yl)pyrroles and a new BODIPY fluorophore (BODIPY = 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene).2-(苯并[b]噻吩-3-基)吡咯及一种新型BODIPY荧光团(BODIPY = 4,4-二氟-4-硼-3a,4a-二氮杂-s-茚)的合成与光学性质
Chemistry. 2009 Jun 2;15(23):5823-30. doi: 10.1002/chem.200802467.
7
Optical effects of S-oxidation and M(n+) binding in meso-thienyl dipyrrin systems and of stepwise bromination of 4,4-difluoro-8-(2,5-dibromo-3-thienyl)-4-bora-3a,4a-diaza-s-indacene.中噻吩基二吡咯体系中S-氧化和M(n+)结合以及4,4-二氟-8-(2,5-二溴-3-噻吩基)-4-硼杂-3a,4a-二氮杂-s-茚的逐步溴化的光学效应。
Inorg Chem. 2008 Dec 1;47(23):11071-83. doi: 10.1021/ic801354y.
8
4-(4,4-Difluoro-1,3,5,7-tetra-methyl-3a-aza-4a-azonia-4-borata-s-indacen-8-yl)benzonitrile.4-(4,4-二氟-1,3,5,7-四甲基-3a-氮杂-4a-氮鎓-4-硼杂-s-茚并[1,2-b]喹啉-8-基)苯甲腈
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):o908. doi: 10.1107/S1600536811009457. Epub 2011 Mar 19.
9
Synthesis and characterization of 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY)-labeled fluorescent ligands for the mu opioid receptor.用于μ阿片受体的4,4-二氟-4-硼-3a,4a-二氮杂-s-茚(BODIPY)标记的荧光配体的合成与表征
Biochem Pharmacol. 1997 Dec 15;54(12):1315-22. doi: 10.1016/s0006-2952(97)00374-2.
10
Synthesis and characterisation of the unsubstituted dipyrrin and 4,4-dichloro-4-bora-3a,4a-diaza-s-indacene: improved synthesis and functionalisation of the simplest BODIPY framework.未取代二吡咯并吡咯及 4,4-二氯-4-硼-3a,4a-二氮杂-s-茚并[1,2-b]吡咯的合成与表征:最简单的 BODIPY 骨架的改进合成与功能化。
Chem Commun (Camb). 2013 Jan 28;49(8):816-8. doi: 10.1039/c2cc37480c.

引用本文的文献

1
Cross-Correlation Between B Quadrupole and B-F Dipole-Dipole Coupling in BF Groups.BF基团中B四极矩与B-F偶极-偶极耦合之间的互相关
Magn Reson Chem. 2025 Mar;63(3):220-226. doi: 10.1002/mrc.5507. Epub 2024 Dec 20.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
"Turn ON/OFF your LOV light": boron-dipyrromethene-flavin dyads as biomimetic switches derived from the LOV domain.
Angew Chem Int Ed Engl. 2005 Apr 8;44(15):2288-91. doi: 10.1002/anie.200462377.
3
Dimers of dipyrrometheneboron difluoride (BODIPY) with light spectroscopic applications in chemistry and biology.二氟化硼二吡咯亚甲基(BODIPY)二聚体及其在化学和生物学中的光谱应用。
J Am Chem Soc. 2002 Jan 16;124(2):196-204. doi: 10.1021/ja010983f.