Li Shu-Xian, Zhu Lin, Li Hua-Min, Fun Hoong-Kun, Chantrapromma Suchada
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 6;64(Pt 9):o1690. doi: 10.1107/S1600536808023726.
In the crystal structure, the title compound, C(12)H(16)N(6)O(6), lies on an inversion centre. The mol-ecule has an anti-periplanar conformation with respect to the C-C bond of the central ethane unit and the two imidazole rings are parallel to each other. The dihedral angle between the imidazole ring and the mean plane of the C and O atoms of the bis-(eth-oxy)ethane group is 76.04 (6)°. The mol-ecules are stacked along the c axis through a weak C-H⋯O inter-action and a π⋯π inter-action between the imidazole rings with a centroid-centroid distance of 3.5162 (6) Å. An intramolecular C-H⋯O hydrogen bond is also present.
在晶体结构中，标题化合物C(12)H(16)N(6)O(6)位于一个对称中心上。分子相对于中心乙烷单元的C-C键具有反式共平面构象，且两个咪唑环相互平行。咪唑环与双（乙氧基）乙烷基团的C和O原子的平均平面之间的二面角为76.04 (6)°。分子通过弱的C-H⋯O相互作用沿c轴堆积，并且咪唑环之间存在π⋯π相互作用，质心间距为3.5162 (6) Å。还存在分子内C-H⋯O氢键。
