• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

N-（2,6-二甲基苯基）苯磺酰胺

N-(2,6-Dimethyl-phen-yl)benzene-sulfonamide.

作者信息

Gowda B Thimme, Foro Sabine, Babitha K S, Fuess Hartmut

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 6;64(Pt 9):o1691. doi: 10.1107/S1600536808024653.

DOI:10.1107/S1600536808024653
PMID:21201680
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2960643/
Abstract

In the crystal structure of the title compound, C(14)H(15)NO(2)S, the N-H bond is trans to one of the S=O double bonds, similar to what is observed in N-(2-methyl-phen-yl)benzene-sulfonamide and other aryl sulfonamides. The two aromatic rings enclose a dihedral angle of 44.9 (1)°. The mol-ecules are connected by inter-molecular N-H⋯O hydrogen bonds into chains running along the a axis. An intermolecular C-H⋯O hydrogen bond is also present.

摘要

在标题化合物C(14)H(15)NO(2)S的晶体结构中，N - H键与其中一个S = O双键呈反式排列，这与在N-(2-甲基苯基)苯磺酰胺及其他芳基磺酰胺中观察到的情况相似。两个芳环间的二面角为44.9 (1)°。分子通过分子间N - H⋯O氢键连接成沿a轴延伸的链。还存在一个分子间C - H⋯O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/36ca/2960643/ded2e9f424f5/e-64-o1691-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/36ca/2960643/da9ee5c5de44/e-64-o1691-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/36ca/2960643/ded2e9f424f5/e-64-o1691-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/36ca/2960643/da9ee5c5de44/e-64-o1691-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/36ca/2960643/ded2e9f424f5/e-64-o1691-fig2.jpg

相似文献

1
N-(2,6-Dimethyl-phen-yl)benzene-sulfonamide.N-（2,6-二甲基苯基）苯磺酰胺
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 6;64(Pt 9):o1691. doi: 10.1107/S1600536808024653.
2
Crystal structures of isomeric 3,5-di-chloro--(2,3-di-methyl-phen-yl)benzene-sulfonamide, 3,5-di-chloro--(2,6-di-methyl-phen-yl)benzene-sulfonamide and 3,5-di-chloro--(3,5-di-methyl-phen-yl)benzene-sulfonamide.同分异构体3,5-二氯-γ-(2,3-二甲基苯基)苯磺酰胺、3,5-二氯-γ-(2,6-二甲基苯基)苯磺酰胺和3,5-二氯-γ-(3,5-二甲基苯基)苯磺酰胺的晶体结构
Acta Crystallogr E Crystallogr Commun. 2017 Apr 11;73(Pt 5):673-677. doi: 10.1107/S2056989017005230. eCollection 2017 May 1.
3
N-(3-Chloro-phen-yl)benzene-sulfonamide.N-（3-氯苯基）苯磺酰胺
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 23;64(Pt 9):o1825. doi: 10.1107/S1600536808026895.
4
4-Methyl-N-{4-[(5-methyl-1,2-oxazol-3-yl)sulfamo-yl]phen-yl}benzene-sulfonamide.4-甲基-N-{4-[(5-甲基-1,2-恶唑-3-基)氨磺酰基]苯基}苯磺酰胺
Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):o693. doi: 10.1107/S1600536812005260. Epub 2012 Feb 17.
5
2,4-Dimethyl-N-(3-methyl-phen-yl)benzene-sulfonamide.2,4-二甲基-N-(3-甲基苯基)苯磺酰胺
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 31;66(Pt 4):o989. doi: 10.1107/S1600536810011529.
6
Crystal structures of trans-di-chlorido-tetra-kis-[1-(2,6-diiso-propyl-phen-yl)-1H-imidazole-κN (3)]iron(II), trans-di-bromido-tetra-kis-[1-(2,6-diiso-propyl-phen-yl)-1H-imidazole-κN (3)]iron(II) and trans-di-bromido-tetra-kis-[1-(2,6-diiso-propyl-phen-yl)-1H-imidazole-κN (3)]iron(II) diethyl ether disolvate.反式二氯代四[1-(2,6-二异丙基苯基)-1H-咪唑-κN(3)]铁(II)、反式二溴代四[1-(2,6-二异丙基苯基)-1H-咪唑-κN(3)]铁(II)以及反式二溴代四[1-(2,6-二异丙基苯基)-1H-咪唑-κN(3)]铁(II)二乙醚溶剂合物的晶体结构
Acta Crystallogr Sect E Struct Rep Online. 2014 Jul 19;70(Pt 8):72-6. doi: 10.1107/S1600536814014056. eCollection 2014 Aug 1.
7
N-(2,3-Dimethyl-phen-yl)benzene-sulfonamide.N-（2,3-二甲基苯基）苯磺酰胺
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 23;65(Pt 2):o366. doi: 10.1107/S1600536809002098.
8
N-(3-Methyl-phen-yl)-2-nitro-benzene-sulfonamide.N-（3-甲基苯基）-2-硝基苯磺酰胺
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):o2627. doi: 10.1107/S1600536812034009. Epub 2012 Aug 4.
9
N-(2,5-Dimethoxy-phen-yl)-4-nitro-benzene-sulfonamide.N-（2,5-二甲氧基苯基）-4-硝基苯磺酰胺
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 22;65(Pt 8):o1939. doi: 10.1107/S1600536809027962.
10
N-(2-Methyl-phen-yl)benzene-sulfonamide.N-（2-甲基苯基）苯磺酰胺
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 6;64(Pt 9):o1692. doi: 10.1107/S1600536808024562.

引用本文的文献

1
N-(2-Hy-droxy-phen-yl)-4-methyl-benzene-sulfonamide.N-（2-羟基苯基）-4-甲基苯磺酰胺
Acta Crystallogr Sect E Struct Rep Online. 2013 Dec 14;70(Pt 1):o54. doi: 10.1107/S1600536813033394. eCollection 2014 Jan 1.
2
4-Chloro-N-(2,6-dimethyl-phen-yl)benzene-sulfonamide.4-氯-N-(2,6-二甲基苯基)苯磺酰胺
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):o1401. doi: 10.1107/S160053681101717X. Epub 2011 May 14.
3
N-(2,6-Dichloro-phen-yl)benzene-sulfonamide.N-（2,6-二氯苯基）苯磺酰胺

本文引用的文献

1
2,4-Dimethyl-phenyl benzoate.苯甲酸2,4-二甲基苯酯
Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 19;64(Pt 7):o1280. doi: 10.1107/S1600536808017480.
2
N-(2-Methyl-phen-yl)benzene-sulfonamide.N-（2-甲基苯基）苯磺酰胺
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 6;64(Pt 9):o1692. doi: 10.1107/S1600536808024562.
3
A short history of SHELX.SHELX简史。
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 6;66(Pt 12):o3061. doi: 10.1107/S160053681004420X.
4
N-(3,4-Dimethyl-phen-yl)-4-methyl-benzene-sulfonamide.N-（3,4-二甲基苯基）-4-甲基苯磺酰胺
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 28;65(Pt 4):o877. doi: 10.1107/S1600536809010459.
5
2,4-Dimethyl-N-phenyl-benzene-sulfonamide.2,4-二甲基-N-苯基苯磺酰胺
Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 21;65(Pt 3):o576. doi: 10.1107/S160053680900573X.
6
N-(2,3-Dimethyl-phen-yl)benzene-sulfonamide.N-（2,3-二甲基苯基）苯磺酰胺
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 23;65(Pt 2):o366. doi: 10.1107/S1600536809002098.
7
N-(3,5-Dichloro-phen-yl)benzene-sulfonamide.N-（3,5-二氯苯基）苯磺酰胺
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 25;64(Pt 11):o2190. doi: 10.1107/S1600536808034351.
8
N-(2,6-Dimethyl-phen-yl)-4-methyl-benzene-sulfonamide.N-（2,6-二甲基苯基）-4-甲基苯磺酰胺
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 24;66(Pt 5):o1168. doi: 10.1107/S1600536810014571.
9
N-(3,5-Dimethyl-phen-yl)benzene-sulfonamide.N-（3,5-二甲基苯基）苯磺酰胺
Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 28;65(Pt 12):o3225. doi: 10.1107/S1600536809050089.
10
N-(2,5-Dimethyl-phen-yl)benzene-sulfonamide.N-（2,5-二甲基-苯基）苯磺酰胺
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 17;65(Pt 11):o2763. doi: 10.1107/S1600536809041841.
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
4
Structural systematics of 4,4'-disubstituted benzenesulfonamidobenzenes. 1. Overview and dimer-based isostructures.4,4'-二取代苯磺酰胺基苯的结构系统学。1. 概述及基于二聚体的同构体
Acta Crystallogr B. 2007 Aug;63(Pt 4):621-32. doi: 10.1107/S010876810701395X. Epub 2007 Jul 17.