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萘-1,5-二磺酸双[双(1H-咪唑-κN)银(I)]盐

Bis[bis(1H-imidazole-κN)silver(I)] naphthalene-1,5-disulfonate.

作者信息

Liu Ping, Deng Dong-Sheng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 14;64(Pt 4):m556. doi: 10.1107/S1600536808006855.

DOI:10.1107/S1600536808006855
PMID:21202012
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2961055/
Abstract

The title compound, Ag(C(3)H(4)N(2))(2)(C(10)H(6)O(6)S(2)), exists in the form of isolated cations and anions with electrostatic inter-action between them. The Ag atom is two-coordinated by the N atoms of two crystallographically independent imidazole mol-ecules. The naphthalene-1,5-disulfonate anion is located on a crystallographic center of symmetry. The cations and anions are connected through inter-molecular N-H⋯O hydrogen bonds.

摘要

标题化合物[Ag(C₃H₄N₂)₂]₂(C₁₀H₆O₆S₂)以孤立的阳离子和阴离子形式存在，它们之间存在静电相互作用。Ag原子由两个晶体学独立的咪唑分子的N原子进行双配位。萘-1,5-二磺酸根阴离子位于晶体学对称中心上。阳离子和阴离子通过分子间N-H⋯O氢键相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b28d/2961055/bfdb3d672bf8/e-64-0m556-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b28d/2961055/02d18ab7c246/e-64-0m556-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b28d/2961055/bfdb3d672bf8/e-64-0m556-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b28d/2961055/02d18ab7c246/e-64-0m556-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b28d/2961055/bfdb3d672bf8/e-64-0m556-fig2.jpg

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