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(E)-4-叔丁基-2-(2,6-二异丙基-苯基-亚氨基-甲基)-6-(吗啉甲基)苯酚

(E)-4-tert-Butyl-2-(2,6-diisopropyl-phenyl-imino-meth-yl)-6-(morpholinometh-yl)phenol.

作者信息

Zhu Zhichen, Cui Jin, Zhang Mingjie

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 29;64(Pt 4):o743. doi: 10.1107/S1600536808007204.

Abstract

In the mol-ecule of the title compound, C(28)H(40)N(2)O(2), the tert-butyl group is disordered over two positions; site-occupation factors were kept fixed at 0.5. The morpholine ring has a chair conformation. Intra-molecular O-H⋯N hydrogen bonding results in the formation of a planar six-membered ring, which is oriented at a dihedral angle of 0.70 (3)° with respect to the adjacent aromatic ring. The dihedral angle between the benzene rings is 67.66 (3)°.

摘要

在标题化合物C(28)H(40)N(2)O(2)的分子中,叔丁基在两个位置上无序;占位因子固定为0.5。吗啉环呈椅式构象。分子内O-H⋯N氢键导致形成一个平面六元环,该六元环相对于相邻的芳香环以0.70 (3)°的二面角取向。苯环之间的二面角为67.66 (3)°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ac8a/2960942/494bbfe084b3/e-64-0o743-fig1.jpg

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