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Bis(μ-2,2'-oxydibenzoato-κO,O':O'',O''')bis-[(4,4'-dimethyl-2,2'-bipyridine-κN,N')zinc(II)] dihydrate.

作者信息

Cui Hong, Li Wen-Juan, Tao Ruo-Jie

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 23;64(Pt 5):m697. doi: 10.1107/S1600536808010271.

Abstract

In the title compound, [Zn(2)(C(14)H(8)O(5))(2)(C(12)H(12)N(2))(2)]·2H(2)O, the Zn(II) atom exhibits a distorted octa-hedral coordination geometry, defined by two N atoms from one 4,4'-dimethyl-2,2'-bipyridine ligand and four O atoms from two bridging 2,2'-oxydibenzoate ligands. The mol-ecule is a centrosymmetric dimer. π-π Stacking inter-actions are observed between the 4,4'-dimethyl-2,2'-bipyridine ligands, with a centroid-centroid distance of 3.649 (2) Å.

摘要

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