链状聚[[溴化铜（I）]-μ-η,σ-3-（2-烯丙基-2H-四唑-5-基）吡啶]
catena-Poly[[bromidocopper(I)]-μ-η,σ-3-(2-allyl-2H-tetra-zol-5-yl)pyridine].
作者信息
Wang Wei
机构信息
Ordered Matter Science Research Center, Southeast University, Nanjing 210096, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 May 3;64(Pt 6):m759. doi: 10.1107/S1600536808010313.
The title compound, CuBr(C(9)H(9)N(5)), has been prepared by the solvothermal treatment of CuBr with 3-(2-allyl-2H-tetra-zol-5-yl)pyridine. It is a new homometallic Cu(I) olefin coord-ination polymer in which the Cu(I) atoms are linked by the 3-(2-allyl-2H-tetra-zol-5-yl)pyridine ligands and bonded to one terminal Br atom each. The organic ligand acts as a bidentate ligand connecting two neighboring Cu centers through the N atom of the pyridine ring and the double bond of the allyl group. A three-dimensional structure is formed through weak Cu-Br [3.1579 (8) Å], C-H⋯Br and C-H⋯N inter-actions.
标题化合物[CuBr(C₉H₉N₅)]ₙ是通过溴化铜与3-(2-烯丙基-2H-四唑-5-基)吡啶进行溶剂热处理制备得到的。它是一种新型的同金属铜(I)烯烃配位聚合物，其中铜(I)原子通过3-(2-烯丙基-2H-四唑-5-基)吡啶配体相连，且每个铜(I)原子均与一个端基溴原子键合。有机配体作为双齿配体，通过吡啶环的氮原子和烯丙基的双键连接两个相邻的铜中心。通过弱的Cu-Br [3.1579 (8) Å]、C-H⋯Br和C-H⋯N相互作用形成三维结构。
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