（E）-2-羟基-3-甲氧基苯甲醛硫代半卡巴腙
(E)-2-Hydr-oxy-3-methoxy-benzaldehyde thio-semicarbazone.
作者信息
Zhao Ren-Gao, Zhang Wei, Li Ji-Kun, Zhang Li-Ya
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 May 17;64(Pt 6):o1113. doi: 10.1107/S1600536808014475.
Abstract
In the title compound, C(9)H(11)N(3)O(2)S, intra-molecular O-H⋯O and N-H⋯N hydrogen bonds contribute to the planarity of the mol-ecular skeleton. Inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into zigzag chains along the b axis; these mol-ecules are futher paired by π-π inter-actions [centroid-centroid distance 4.495 (5) Å]. The crystal structure also exhibits weak inter-molecular N-H⋯S and O-H⋯S hydrogen bonds.
摘要
在标题化合物C₉H₁₁N₃O₂S中，分子内的O—H⋯O和N—H⋯N氢键有助于分子骨架的平面性。分子间的N—H⋯O氢键将分子沿b轴连接成锯齿链；这些分子通过π-π相互作用进一步配对[质心-质心距离4.495 (5) Å]。晶体结构还表现出较弱的分子间N—H⋯S和O—H⋯S氢键。
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