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8-溴萘-1-胺

8-Bromo-naphthalen-1-amine.

作者信息

Fuller Amy L, Knight Fergus R, Slawin Alexandra M Z, Woollins J Derek

机构信息

Department of Chemistry, University of St Andrews, St Andrews KY16 9ST, Scotland.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 May 3;64(Pt 6):o977. doi: 10.1107/S1600536808012580.

DOI:10.1107/S1600536808012580
PMID:21202706
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2961535/
Abstract

The title compound, C(10)H(8)BrN, was obtained by slow addition of sodium azide to 8-bromo-1-naphthoic acid, followed by addition of aqueous ammonia. The crude product was crystallized from petroleum ether to give pink crystals. Compared to other 1,8-disubstituted naphthalene compounds, this compound exhibits less strain between the 1 and 8 substituents. Additionally, the NH protons form both intra- and inter-molecular hydrogen bonds. The naphthalene units are arranged in a herring-bone stacking motif.

摘要

标题化合物C(10)H(8)BrN是通过将叠氮化钠缓慢加入到8-溴-1-萘甲酸中，然后加入氨水制得的。粗产物从石油醚中结晶得到粉红色晶体。与其他1,8-二取代萘化合物相比，该化合物在1和8取代基之间表现出较小的张力。此外，NH质子形成分子内和分子间氢键。萘单元以人字形堆积模式排列。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d06/2961535/89e6f9fd384e/e-64-0o977-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d06/2961535/6b047b1e5721/e-64-0o977-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d06/2961535/89e6f9fd384e/e-64-0o977-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d06/2961535/6b047b1e5721/e-64-0o977-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d06/2961535/89e6f9fd384e/e-64-0o977-fig2.jpg

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