Liu Chunyi, Zhou Anyu, Wang Songpei, Chen Zhengping
Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 13;64(Pt 7):m914-5. doi: 10.1107/S1600536808017273.
In the title complex, Cu(C(3)H(4)N(2))(C(10)H(11)N(3))(2)(2), the Cu(II) cation has a distorted trigonal-bipyramidal geometry defined by a CuN(2)N'(2)N'' donor set. The imidazole ligand is disordered over two orientations of equal occupancy. Two of the perchlorate ion sites are located on a twofold rotation axis, and one of is disordered over two sites of equal occupancy. In the crystal structure there is a two-dimensional infinite network of hydrogen-bonded mol-ecules parallel to the ab plane.
在标题配合物Cu(C₃H₄N₂)(C₁₀H₁₁N₃)₂₂中，Cu(II)阳离子具有由CuN₂N′₂N″供体集定义的扭曲三角双锥几何构型。咪唑配体在两个占有率相等的取向上无序。两个高氯酸根离子位点位于二重旋转轴上，其中一个在两个占有率相等的位点上无序。在晶体结构中，存在一个与ab平面平行的二维无限氢键分子网络。
