二氯（甲醇 - κO）[2 - （2 - 吡啶基甲氧基）- 1,10 - 菲咯啉 - κN，N'，N'']锰（II）
Dichlorido(methanol-κO)[2-(2-pyridyl-meth-oxy)-1,10-phenanthroline-κN,N',N'']manganese(II).
作者信息
Li Hong Liang, Chao Hou
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 25;64(Pt 7):m962. doi: 10.1107/S1600536808018631.
Abstract
In the title mononuclear complex, [MnCl(2)(C(18)H(13)N(3)O)(CH(4)O)], the Mn(II) ion assumes a distorted octa-hedral geometry. There is a π-π stacking inter-action between the phenanthroline ligand and the pyridine ring of a neighboring complex [centroid-to-centroid distance 3.5518 (13) Å]. The crystal structure also contains weak inter-molecular O-H⋯Cl hydrogen bonds that link neighboring complex mol-ecules into a one-dimensional chain along the b axis.
摘要
在标题单核配合物[MnCl₂(C₁₈H₁₃N₃O)(CH₄O)]中，Mn(II)离子呈扭曲的八面体几何构型。菲咯啉配体与相邻配合物的吡啶环之间存在π - π堆积相互作用[质心到质心距离为3.5518 (13) Å]。晶体结构中还存在弱的分子间O - H⋯Cl氢键，这些氢键将相邻的配合物分子沿b轴连接成一维链。
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