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4,4'-二甲氧基二苯甲酮:一种三斜多晶型物。

4,4'-Dimethoxy-benzophenone: a triclinic polymorph.

作者信息

Fun Hoong-Kun, Franklin S, Jebas Samuel Robinson, Balasubramanian T

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 13;64(Pt 7):o1256. doi: 10.1107/S1600536808017315.

Abstract

The title compound, C(15)H(14)O(3), has been found to crystallize as a new triclinic polymorph. The asymmetric unit of the present structure, as in the previously reported monoclinic structure [Norment & Karle (1962 ▶). Acta Cryst. 15, 873-878], contains two independent mol-ecules, which differ slightly in the orientations of the two benzene rings. The crystal packing of the triclinic polymorph is stabilized by inter-molecular C-H⋯O hydrogen bonds and C-H⋯π inter-actions.

摘要

已发现标题化合物C(15)H(14)O(3)以一种新的三斜晶型多晶型物形式结晶。与先前报道的单斜晶型结构[诺门特和卡尔(1962年▶)。《晶体学报》,15,873 - 878]一样,当前结构的不对称单元包含两个独立分子,这两个分子的两个苯环取向略有不同。三斜晶型多晶型物的晶体堆积通过分子间C - H⋯O氢键和C - H⋯π相互作用得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81fb/2961821/8ba5ab505297/e-64-o1256-fig1.jpg

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