Haider Zeeshan, Arshad Muhammad Nadeem, Zia-Ur-Rehman Muhammad, Khan Islam Ullah, Shafiq Muhammad
Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 18;65(Pt 12):o3107. doi: 10.1107/S160053680904762X.
The crystal structure of the title compound, C(14)H(21)NO(2)S, is a polymorph of the structure reported by Khan et al. [Acta Cryst. (2009), E65, o2867] which is also monoclinic (space group P2(1)/c). The unit cell in the title structure is approximately half the volume of the previously reported polymorph and the asymmetric unit of the title compound contains one mol-ecule rather than two independent mol-ecules in the other polymorph. In the title mol-ecule, the cyclo-hexane ring is in the typical chair form. In the crystal structure, mol-ecules are linked via weak inter-molecular C-H⋯O inter-actions, forming a chain along the b-axis direction.
标题化合物C(14)H(21)NO(2)S的晶体结构是Khan等人[《晶体学报》(2009年),E65,o2867]报道的结构的一种多晶型物,该结构也是单斜晶系(空间群P2(1)/c)。标题结构中的晶胞体积约为先前报道的多晶型物的一半,且标题化合物的不对称单元包含一个分子,而非另一种多晶型物中的两个独立分子。在标题分子中,环己烷环呈典型的椅式构象。在晶体结构中,分子通过弱分子间C-H⋯O相互作用相连,沿b轴方向形成一条链。